the solubility of kno3 in the mixed solvent (water 85%+methanol 15%) were determined by using solvent evaporating method at different temperatures (25, 30, 40, 50, 60 ;c). in addition the equilibrium constant of ion pair formation, kip, for k+no3 – ion-pair on the basis of fuoss contact ion pair model was calculated. upon choosing the extended debye-hückel model for estimating the mean activity...

The Gibbs conditions of stable thermodynamic equilibrium are formulated for nonlinear thermoelastic materials, based on the constrained minimization of four fundamental thermodynamic potentials. Sufficient conditions for incremental stability are stated in each case. The previously unexplored connections between the second-order variations of thermodynamic potentials are used to establish the c...

1. The equilibrium constant for oxidative decarboxylation of isocitrate by NADP(+), catalysed by isocitrate dehydrogenase, was measured in solutions of various ionic strengths and at several temperatures. 2. Thermodynamic values for the reaction were obtained by extrapolation to zero ionic strength, and the heat of reaction was estimated. 3. The effect of Mg(2+) ion concentration on the equilib...

an ion imprinted polymer (iip) based on aniline-formaldehyde was synthesized and then modified with extra aniline as cross-linker in the presence and absence of sr (ii) as the template to produce ion imprinted poly(aniline-formaldehyde) (iipaf) and non imprinted poly(aniline-formaldehyde) (nipaf). the sorbent was characterized by fourier transform infrared spectroscopy and was used for solid ph...

We apply the formalism of geometrothermodynamics to the case of black holes with cosmological constant in four and higher dimensions. We use a thermodynamic metric which is invariant with respect to Legendre transformations and determines the geometry of the space of equilibrium states. For all known black holes in higher dimensions, we show that the curvature scalar of the thermodynamic metric...

The thermodynamic model of ultrathin lubricant film melting, confined between two atomically-flat solid surfaces, is built using the Landau phase transition approach. Non-equilibrium entropy is introduced describing the part of thermal motion conditioned by non-equilibrium and non-homogeneous character of the thermal distribution. The equilibrium entropy changes during the time of transition of...

We apply the formalism of geometrothermodynamics to the case of black holes with cosmological constant in four and higher dimensions. We use a thermodynamic metric which is invariant with respect to Legendre transformations and determines the geometry of the space of equilibrium states. For all known black holes in higher dimensions, we show that the curvature scalar of the thermodynamic metric...

An ion imprinted polymer (IIP) based on aniline-formaldehyde was synthesized and then modified with extra aniline as cross-linker in the presence and absence of Sr (II) as the template to produce ion imprinted poly(aniline-formaldehyde) (IIPAF) and non imprinted poly(aniline-formaldehyde) (NIPAF). The sorbent was characterized by Fourier Transform Infrared Spectroscopy and was used for solid ph...