neutral bidentate n-o type complexe of vo(ii) has been synthesized through condensation of dpenicillamine,(d-h2pen), with bis(acetylacetonate)- oxovanadium(iv),[vo(acac)2], at neutralmedium . the established schiff base(no type) complex was characterized on the basis of ir andmass spectroscopy techniques.besides,d-h2pen binding behavior to[vo(acac)2] has been studiedin thermodynamic viewpoint u...

the adsorption thermodynamic characteristic of cu2+ from aqueous solution onto humin andalso humic acid from a typical black soil in northeast china were examined at three different temperatures(298, 318 and 338 k) by batch isotherm experiments. results showed that humin was structurally differentfrom humic acid. the increase of temperature had a positive effect on the adsorption process. freun...

the binding energy and thermodynamic parameters of cis- platinum di ammino chlorine (cis-[pt(nh3)2cl]+) and trans- platinum di ammino chlorine (trans- [pt(nh3)2cl]+) complexes withguanine has been studied by density functional theory (dft) calculations in water. the bindingenergies (ebin) of cis- and trans-[pt(nh3)2clg]+ are calculated to be 79.38 kcal/mol and 74.98kcal/mol, respectively. the b...

some new symmetrical tetraaza schiff base ligands containing 2-quinolinecarboxaldehyde moiety formed from condensation reaction of 2-quinolinecarboxaldehyde and o-phenylenediamine derivatives, such as n, nˊ-bis(2-quinolylmethylidene)-4-methoxy-1, 2-phenylenediimine (l1), n, nˊ-bis(2-quinolylmethylidene)-4-methy-1, 2-phenylenediimine (l2), n, nˊ-bis(2-quinolylmethylidene)-4-chloro-1, 2-phenylene...

in this study, the response is derived, high-energy material 1-(4-nitrophenyl)-1h-tetrazole (npht) with boron nitridenano-cages in different conditions of temperature, density functional theory methods were studied. for this purpose, the material on both sides were geometrically optimized, then the calculation of the thermodynamic parameters were performed on all of them. the amount of δh, δs a...

in this study some thermodynamic parameters including freezing point, boiling point and the vapor pressure of urmia lake salt water were investigated as some important environmentally monitored physicochemical properties of urmia lake. in this regard salt concentration is chiefly responsible for the modification of the thermodynamic properties of urmia lake water which affects its overall en...

in this study some thermodynamic parameters including freezing point, boiling point and the vapor pressure of urmia lake salt water were investigated as some important environmentally monitored physicochemical properties of urmia lake. in this regard salt concentration is chiefly responsible for the modification of the thermodynamic properties of urmia lake water which affects its overall envir...