Chiral binaphthyl-linked subphthalocyanines (SubPcs) (1) have been prepared by the cyclotrimerization reaction of a phthalonitrile linked with (R)- and (S)-2,2'-binaphthyl in the presence of BCl3, and characterized by various spectroscopies including NMR, electronic absorption, CD, and MCD, as well as electrochemistry.

Over the past decade, bipolar electrochemistry has emerged from relative obscurity to provide a promising new means for integrating electrochemistry into lab-on-a-chip systems. This article describes the fundamental operating principles of bipolar electrodes, as well as several interesting applications.

A microreactor for electrochemical synthesis has been designed and fabricated. It has been shown that different reactions can be carried out successfully using simple protocols.

Electron paramagnetic resonance and electrochemistry are used to evidence the interaction between 1,10-phenanthroline (Phen) and KO(t)Bu to form the 1,10-phenanthroline radical anion, Phen˙(-), and the (t)BuO˙ radical via an inner-sphere electron transfer. In addition, electrochemistry is also used to explain the formation of aryl radicals from aryl bromides via outer-sphere electron transfer f...

Milica M. Gvozdenović1,*, Branimir Z. Jugović2, Jasmina S. Stevanović3, Tomislav Lj. Trišović2 and Branimir N. Grgur1 1Department of Physical Chemistry and Electrochemistry, Faculty of Technology and Metallurgy, University of Belgrade, Belgrade, 2Institute of Technical Sciences, Serbian Academy of Science and Arts, 3Center for Electrochemistry, Institute of Technology and Metallurgy, Belgrade S...