A flow injection (FI) system was used to develop an efficient on-line sorbent extraction preconcentration system for palladium by graphite furnace atomic absorption spectrometry (GFAAS). The investigated metal was preconcentrated on a microcolumn packed with 1,5-bis(di-2-pyridyl)methylene thiocarbohydrazide immobilized on silica gel (DPTH-gel). The palladium is eluted with 40mul of HCl 4M and d...

In this research the polymer which contains aldehyde group [H1] has been prepared by oxidation [H] using oxidizing agent (Dess Martin Periodinane), dialyzed ethanol, Schiff bases[H2,H5andH8] compounds have through reaction of compound with appropriate amines, [H3] hydroquinazolin ring [H2] 2-amino benzoic acid.[H4]which cyclization phthalic anhydride. [H6,H7]were [H5] acid and anhydriede. React...

Simultaneous condensation reaction of thiocarbohydrazide with simple aromatic aldehyde and highly reactive ferrocenecarboxaldehyde resulted unusual unsymmentric Schiff bases associated multi metal ion sensing property. Spectral characterization methods indicate the formation new materials. Guest- host relationship established between various ions receptors changes electronic spectra drastically...

The increasing use of automobile catalysts leads to the emission of the platinum-group elements (PGE), mainly platinum, but also rhodium and palladium into the environment. In environmental samples, the low concentration of platinum together with the high concentration of interfering matrix components often requires a preconcentration/enrichment step combined with a matrix-separation. The metho...

The reaction of thiocarbohydrazide with substituted phenoxy acetic acid to obtained 3substituted-4-amino-5-mercapto-1,2,4-triazoles (1) by condensing compound 1 with aromatic carboxylic acid and substituted phenoxy acetic acids resulted the title compound triazolothiadiazoles 2a-j. The purity of the newly synthesized compounds was confirmed by TLC. Structures of all the newly synthesized compou...

A fully automated procedure for the determination of rhodium has been developed using flow injection (FI) on-line microcolumn preconcentration coupled with electrothermal atomic absorption spectrometry (ETAAS). The proposed FI manifold and its operation make possible the introduction of the total eluate volume into the graphite atomizer, avoiding the necessity for optimisation of subsampling th...