Recent studies on the intercalation and exfoliation of layered clays with polymeric intercalating agents involving poly(oxypropylene)-amines and the particular uses for epoxy nanocomposites are reviewed. For intercalation, counter-ionic exchange reactions of clays including cationic layered silicates and anionic Al-Mg layered double hydroxide (LDH) with polymeric organic ions afforded organocla...

This review reports recent advances in the field of polymer–layered silicate nano composites. Thesematerials have attracted both academic and industrial attention because they exhibit dramaticimprovement in properties at very low filler contents. Herein, the structure, preparation andproperties of polymer–layered silicate nanocomposites are discussed in general, and finally the effectof clay na...

A quantitative description is presented of the dynamical process of polymer intercalation into clay tactoids and the ensuing aggregation of polymer-entangled tactoids into larger structures, obtaining various characteristics of these nanocomposites, including clay-layer spacings, out-of-plane clay-sheet bending energies, X-ray diffractograms, and materials properties. This model of clay-polymer...

Sorption-desorption of two different hydrophobic fungicides, penconazole and metalaxyl, by a series of clay minerals layered and non-layered (montmorillonite, illite, kaolinite, muscovite, sepiolite and palygorskite) modified with the two-chain cationic surfactant, dihexadecyldimetylammonium (DHDDMA) was studied by first time in this work. DHDDMA-clays showed a good capacity to sorb both fungic...

In order to make virtual modeling as easy as real clay manipulation, we describe a realtime virtual clay model, specially designed for direct hand manipulation. We build on a previous layered model for clay, extending it to handle local properties such as colour or fluidity, to deal with an arbitrary number of tools, and to capture twist effects due to rotating tools. The resulting clay model i...

[1] Phyllosilicates have previously been detected in layered outcrops in and around the Martian outflow channel Mawrth Vallis. CRISM spectra of these outcrops exhibit features diagnostic of kaolinite, montmorillonite, and Fe/Mg-rich smectites, along with crystalline ferric oxide minerals such as hematite. These minerals occur in distinct stratigraphic horizons, implying changing environmental c...

this study was conducted to enhance the antimicrobial properties and water absorption of sanitary papers. for this purpose, montmorillonite nano clay with bentonite brand (has a layered structure in which its thickness is nano metric), was processed with homogenizer to achieve a stable colloidal system with nanometer dimensions of particle size. then, different weight levels of raw and homogeni...

Organically modified clay was used as reinforcement for HDPE using maleated polyethylene (PEMA) as a compatibilizer. The effect of compatibilizer concentration on the orientation of various structural features in the polymer-layered silicate nanocomposite (PLSN) system was studied using two-dimensional (2D) small angle X-ray scattering (SAXS) and 2D wide-angle X-ray scattering (WAXS). The dispe...

In this study, ZnO/SiO2-clay heterostructures were successfully synthesized by a facile two-step process applied to two types of clays: montmorillonite layered silicate and sepiolite microfibrous clay mineral. In the first step, intermediate silica-organoclay hybrid heterostructures were prepared following a colloidal route based on the controlled hydrolysis of tetramethoxysilane in the presenc...