The relationship of merA gene expression (specifying the enzyme mercuric reductase) to mercury volatilization in aquatic microbial communities was investigated with samples collected at a mercury-contaminated freshwater pond, Reality Lake, in Oak Ridge, Tenn. Levels of merA mRNA transcripts and the rate of inorganic mercury [Hg(II)] volatilization were related to the concentration of mercury in...

Phytoremediation is potentially effective for managing excessive selenium (Se) in drainage sediment residing in the San Luis Drain in central California. This 2-year field study examined the feasibility of amending drainage sediment (containing 4.78microgSeg(-1)) with methionine and casein to enhance volatilization without or with vegetation of Sporobolus airoides. Results show that without org...

Estimation of pesticide volatilization from plants is difficult because of our poor understanding of foliar penetration by pesticides, which governs the amount of pesticide available for volatilization from the leaf surface. The description of foliar penetration is still incomplete because experimental measurements of this complex process are difficult. In this study, the dynamics of leaf penet...

The rate of volatilization of dinoseb may depend on soil acidity, temperature, surface soil moisture, the method of application, and the type of formulation (Kaufman 1976). Cohen et al. (1984) reported a volatilization half-life of 26 d. The significance of volatilization has been evidenced by the killing of plants by dinoseb vapours (Davis et al. 1954). Photodegradation is a major fate process...

Pesticide volatilization from agricultural soils is one of the main pathways in which pesticides are dispersed in the environment and affects ecosystems including human welfare. Thus, it is necessary to have accurate knowledge of the various physical and chemical mechanisms that affect volatilization rates from field soils. A verification of the influence of soil moisture modeling on the simula...

This research was conducted with Biscayne marl soil and Krome gravelly loam from Florida and Quincy fine sand and Warden silt loam from Washington to determine ammonia (NH3) volatilization at various temperature and soil water regimes. Potassium nitrate (KNO3), ammonium nitrate (NH4NO3), ammonium sulfate [(NH4)2SO4], or urea were applied to the soil at a rate of 75 kg N ha . Soil water regime w...

An axenically cultured isolate of single-celled freshwater microalgae (Chlorella sp.) metabolized toxic selenate to volatile dimethylselenide at exceptionally high rates when transferred from mineral-nutrient solution to water for 24 h. The Se-volatilization rates were orders of magnitude higher than those similarly measured for wetland macroalgae and higher plants. Ninety percent of 20 micro m...

Soil drought, that can be enhanced by global warming increases ammonia (NH3) volatilization. This laboratory study was conducted with two soils: Krome Gravelly Loam (KGL) from Florida and Warden Silt Loam (WSL) from Washington State and two fertilizers: Ammonium sulfate [(NH4)2SO4] or ammonium nitrate (NH4NO3). Two water regimes including 20 and 80% Field Capacity (FC) were used at 20°C which i...

Cattle slurry was surface-applied to bare soil in two experiments in the period September­ November 1987, while in April-May 1988 two experiments were carried out in which the slur­ ry was mixed with the upper 6 an of the soil with a cultivator immediately after spreading. The 1987 experiments both lasted 18 days, the 1988 experiments 9 days. A micrometcorologi· cal technique, which did not dis...