Here we report the theory and experimental study of the steady-state voltammetric behavior of a microelectrode used as a limiting pole in a closed bipolar electrochemical cell. We show that the steady-state voltammetric response of a microelectrode used in a closed bipolar cell can be quantitatively understood by considering the responses of both poles in their respective conventional two-elect...

There are numerous examples in the literature of amphiphilic molecules which, when adsorbed onto mercury electrodes, undergo electric-field-induced transitions between different molecular conformations. In general, very sharp and reversible voltammetric features associated with these transitions are observed when the electrode potential is scanned in the negative direction, typically over the r...

Citation: Han H, Pan D, Liu D, Hu X, Lin M and Li F (2015) Cathodic stripping voltammetric determination of chromium in coastal waters on cubic Nano-titanium carbide loaded gold nanoparticles modified electrode. Front. Mar. Sci. 2:75. doi: 10.3389/fmars.2015.00075 Cathodic stripping voltammetric determination of chromium in coastal waters on cubic Nano-titanium carbide loaded gold nanoparticles...

A simple square-wave adsorptive voltammetric (SWAV) method was developed for determining Captopril (CAP) in pharmaceutical formulations. The proposed method was based on the electrochemical reduction of CAP at a mercury thin film electrode (MTFE). The preparation of the TMFE/Glassy carbon electrode was very simple; also, this electrode had very good reproducibility and regeneration of its surfa...

Bruland, K.W., Coale, K.H. and Mart, L., 1985. Analysis of seawater for dissolved cadmium, copper and lead: an intercomparison of voltammetric and atomic absorption methods. Mar. Chem., 17: 285--300. An intercomparison study of voltammetric and atomic absorption spectrometric methods for determining cadmium, lead and copper in seawater samples was conducted. The voltammetric approach utilizes d...

In this review, we will briefly outline the voltammetric investigations of the transfer of ionisable drugs at the interface between two immiscible electrolyte solutions. The voltammetric techniques enable the determination of some key in vitro properties of ionisable drugs, including partition coefficient, diffusion coefficient and membrane permeability. Some successful applications will be hig...

An automated device for voltammetric measurements at a prescribed set of constant temperatures was put together in our institute. It allows one to take steady-state current-potential curves in the potentiostatic or galvanostatic mode, to do cyclic voltammetry or coulometry at constant potential or to measure the potential-time dependence at a constant current. A special holder for the solid ele...

In this work, we study electrochemical behavior of p-chloranil as a suitable mediator for voltammetric determination of dopamine (DA) using voltammetric method. Using the modified electrode, the kinetics of DA electrooxidation was considerably enhanced by lowering the anodic over potential through a catalytic fashion. The differential voltammetric peak currents of the electrode increased linear...

In electrochemical sensing, a number of voltammetric or amperometric curves are obtained which are subsequently processed, typically by evaluating peak currents and peak potentials or wave heights and half-wave potentials, frequently after background correction. Transformations of voltammetric data can help to extract specific information, e.g., the number of transferred electrons, and can reve...

The present study reports voltammetric reduction of nitazoxanide in Britton-Robinson (B-R) buffer by cyclic and square-wave voltammetry at glassy carbon electrode. A versatile fully validated voltammetric method for quantitative determination of nitazoxanide in pharmaceutical formulation has been proposed. A squrewave peak current was linear over the nitazoxanide concentration in the range of 2...