Recent progress in the theory and practice of voltammetry is surveyed and evaluated. The transformation over the last decade of the level of modelling and simulation of experiments has realised major advances such that electrochemical techniques can be fully developed and applied to real chemical problems of distinct complexity. This review focuses on the topic areas of: multistep electrochemic...

The combination of graphene and nickel oxide nanoparticles yields nanostructured electrochemical sensor formed a novel kind of structurally uniform and electrocatalytic activity material. In cyclic voltammetry studies, in the presence of epinephrine, nickel oxide / graphene  composite modified electrode shows a significantly higher current response for epinephrine oxidation. Based on differenti...

Essential to the renewal of interest in polarography and voltammetry in the 1970s were the availability of reliable polarographs offering the pulse mode, with sensitivity down to lo-‘-lo-* M and h’gh 1 er resolving power; a better understanding of the electrode processes of compounds of pharmaceutical interest (active agents, excipients, additives, antioxidants, etc.); and the application of ox...

The association of 5',8-cyclo-2'-deoxyguanosine (cdG), a DNA tandem lesion, with its complementary base cytosine has been studied by voltammetry and NMR in chloroform, using properly silylated derivatives of the two nucleobases for increasing their solubilities. Both voltammetric data and NMR titrations indicated that the Watson-Crick complex of cytidine with cdG is weaker than that with guanos...

This paper deals with the development of an electrochemical sensor base on Trypan Blue (TB) towards the determination of Dopamine (DA). An electrochemical sensor was fabricated by the electropolymerization of TB onto the Carbon paste electrode (CPE) using cyclic voltammetry (CV) technique. The polymerized TB modified CPE (Poly(TB)MCPE) was characterized using Electrochemical impedance spectrosc...

We report here on differential linear scan voltammetry, DLSV, that combines the working principles of linear scan voltammetry, LSV, and the numerous existing pulsed voltammetry techniques. DLSV preserves the information from continuous interrogation in voltage and high accuracy that LSV provides about electrochemical processes, and the much better sensitivity of differential pulsed techniques. ...

Development of an in situ technique for measuring electrochemical impedance spectra in real time during an electrochemical experiment is described. The technique is based on staircase voltammetry with relatively large step heights, in which a series of increasing potential steps are applied to an electrochemical system, and the resulting currents are sampled. The first derivatives of the curren...

The interaction of phospholipid membranes and oligonucleotides complexed with a positively charged surfactant is reported. Phospholipid membranes were assembled at the interface between an immobilized organic phase and an aqueous phase using the Langmuir-Blodgett (L-B) technique. The interaction and adsorption of the naked oligonucleotides and oligonucleotides complexed with cetylpyridinium chl...

A graphene-based carbon ionic liquid electrode modified with gold nanoparticles was fabricated. The electrochemical response of the modified electrode toward celecoxib was studied by means of cyclic voltammetry and differential pulse voltammetry. The structural morphology of the modified electrode was characterized by a scanning electron microscopy technique and electrochemical impedance spectr...