Chitosan, a natural polysaccharide, has increasingly been studied as an adsorbent for heavy metal removal in recent years. The amine groups in chitosan are generally known to be the main adsorption sites for heavy metal ions. However, due to the instability of chitosan in acidic solutions, chemical crosslinking has often been used to enhance the acidic resistance of the material. Since most of ...

in present research work, homogeneous anion exchange membranes based on polysulfone (qapsfs) were prepared via chloromethylation, amination and alkalization. in amination step, trimethylamine and n,n,n',n'-tetramethyl-1,6-hexanediamine were used as amination and crosslinking agents, respectively. the chloromethylated polysulfone was characterized by 1hnmr spectroscopy and chloromethylation degr...

We report a facile new route for the synthesis of self-crosslinked anion exchange membranes (AEM) without the need for any crosslinkers or catalysts. The soluble copolymers bearing flexible side chains, with alkene pendant groups, were synthesized via the Menshutkin reaction. The crosslinked derivatives were then prepared by the thermal crosslinking of the unsaturated side chains during the mem...

Gliadin was reacted with citric acid under weak acidic and weak alkaline conditions in both wet and dry states and the reaction mechanism was studied. The low morphological stability in an aqueous environment and inferior mechanical properties have restricted the applications of plant proteins, although these materials possess a unique structure, biocompatibility and biodegradability. Carboxyli...

Abstract Nowadays, coating materials must meet high demands in terms of mechanical, chemical and optical properties all areas application. Amongst others, amines isocyanates are used as crosslinking components for curing reactions, meeting the highly demanding coatings industry. In this work, a new reaction based on oxazoline chemistry is investigated with objective to overcome disadvantages es...

Collagen is extensively used in fabrication of hydrogels for biomedical applications but needs improvement after its isolation from tissues due to slow gelation and poor mechanical properties. Crosslinking could tailor such has previously been crosslinked by chemical or photochemical methods. Chemical crosslinkers are often toxic, the crosslinking reaction difficult control. Photochemical usual...

To improve the mechanical strength and antipollution properties of membranes, this research presents a facile method to prepare crosslinked polyacrylonitrile (PAN) membranes. This was achieved firstly by radical copolymerization with acrylonitrile, allyl methacrylate and sulfobetaine methacrylamide. Then, the copolymer was crosslinked by a thiol-ene click reaction under UV irradiation. Finally,...

The present study shows that the sulfur of the phosphorothioate 5'-nucleoside diphosphate beta-S adds across the olefinic double bond of the maleimide moiety of the thiol-sensitive probe, N-l pyrene maleimide. The reaction of phosphorothioate with the maleimide moiety provided a basis for coupling the phosphorothioate nucleoside diphosphate beta-S to maleimidederivatized bovine serum albumin. F...

Monodisperse alginate microgels (10-50 μm) are created via droplet-based microfluidics by a novel crosslinking procedure. Ionic crosslinking of alginate is induced by release of chelated calcium ions. The process separates droplet formation and gelation reaction enabling excellent control over size and homogeneity under mild reaction conditions. Living mesenchymal stem cells are encapsulated an...