The isomers of xylene have been separated by enclathration using three host compounds: 9,9'-bianthryl (H1), 9,9'-spirobifluorene (H2) and trans-2,3-dibenzoylspiro[cyclopropane-1,9-fluorene] (H3). The structures of each host with a single xylene isomer have been elucidated and, for H1, the relative lattice energies of the clathrates with ortho- and para-xylene have been evaluated.

nanoporous graphene which is used as nanosorbent was synthesized by chemical vapor deposition method via porous zinc oxide nanocatalyst. the reaction was carried out using methane as the carbon source and hydrogen as the carrier gas in a ratio of 4:1 at the temperature ranging 900-1050°c for 2-50 min. the product was characterized by scanning electron microscopy, transmission electron microscop...

A microbial consortium derived from a gasoline-contaminated aquifer was enriched on toluene (T) in a chemostat at 20 degrees C and was found to degrade benzene (B), ethylbenzene (E), and xylenes (X). Studies conducted to determine the optimal temperature for microbial activity revealed that cell growth and toluene degradation were maximized at 35 degrees C. A consortium enriched at 35 degrees C...

Enrichment cultures obtained from soil exposed to benzene, toluene, and xylene (BTX) mineralized benzene and toluene but cometabolized only xylene isomers, forming polymeric residues. This observation prompted us to investigate the metabolism of 14C-labeled BTX hydrocarbons in soil, either individually or as mixtures. BTX-supplemented soil was incubated aerobically for up to 4 weeks in a sealed...

BTX compounds (Benzene, toluene and xylenes) are the main pollutants in air and fuels. Recent environmental legislations are limited the amount of these materials specially the amount of benzene in gasoline due to its carcinogen effects on health. In this research, the BTX hydrogenation was carried out using nanoparticles of Co supported on MWCNTs (multiwall carbon nanotubes) and AC (activated ...

The soil fungus Cladophialophora sp. strain T1 (= ATCC MYA-2335) was capable of growth on a model water-soluble fraction of gasoline that contained all six BTEX components (benzene, toluene, ethylbenzene, and the xylene isomers). Benzene was not metabolized, but the alkylated benzenes (toluene, ethylbenzene, and xylenes) were degraded by a combination of assimilation and cometabolism. Toluene a...

A short primer on benzene, toluene, ethylbenzene and xylenes (BTEX) in the environment and in hydraulic fracturing fluids Dr Frederic Leusch and Dr Michael Bartkow, Griffith University – Smart Water Research Centre 17 Nov 2010 1. Some notes about concentrations Concentrations in water in this document are generally given as part‐per‐billion (ppb), equivalent to one microgram per litre (μg/L). ...

Children spend a large amount of time in school environments and when Indoor Air Quality (IAQ) is poor, comfort, productivity and learning performances may be affected. The aim of the present study is to characterize IAQ in a primary school located in Taranto city (south of Italy). Because of the proximity of a large industrial complex to the urban settlement, this district is one of the areas ...