The adsorption of CO on polycrystalline TiO2 was investigated by static adsorption microcalorimetry. The initial differential heat of adsorption (qdiff,0) of CO on polycrystalline titania is 40 kJ/mol, and the standard adsorption entropy (Deltas0) is -104 J mol(-1) K(-1). These results are consistent with those derived from temperature-programmed desorption and FTIR results in the literature. T...

Rice husk carbon (RHC) has been prepared from rice husk impregnated with 50% H3P04 and carbonised at 300°C. Its adsorption capacity has been tested for the decolourization of wastewater containing safranine and methylene blue. The effect of system variables such as concentration, temperature, pH, contact time, adsorbent dosage and particle size are investigated. Removal of dye has been found to...

The automated procedure for the monitoring of the adsorption process in the solute-sorbent-solvent system has been elaborated. It uses commercially available instrument CRYSTAF model 200. The application of CRYSTAF enabled monitoring of adsorption of linear polyethylene with weight average molar masses of 2, 14, and 53 kg/mol from 1,2,4-trichlorobenzene onto zeolite SH-300 at temperature as hig...

Here we present a statistical mechanical lattice model which is exactly solvable using a matrix method and allows treatment of adsorption induced gate opening structural transformations of metal-organic frameworks which are nanoporous materials with exceptional adsorption properties. Modelling of these structural changes presents a serious theoretical challenge when the solid and gas species ar...

In this study, Saccharum bengalense(SB) was used as biosorbent for the removal of Mn (II) ions from aqueous solution. The influence of biosorbent dose, time, pH and temperature was investigated in the biosorption process. Studies showed that by increasing pH of the solution, metal removing efficiency of Saccharum bengalensefrom the aqueous environment was enhanced but to a specific extent, ...

conclusions according to the high efficiency of cadmium elimination by tea waste, this approach is applicable as an efficient and affordable trend to remove cadmium from aqueous solution without any chemical or physical pre-treatment. background heavy metals pollution is a serious threat to environment and human health. therefore, it is vital to find an effective method to remove heavy metals f...

This investigation was undertaken to determine whether desorption hysteresis effects were dependent upon methods used in obtaining desorption data. Adsorption-desorption isotherms were obtained for two organophosphorus insecticides in aqueous suspensions of a clay, a sandy loam, and an organic soil. Desorption isotherms were obtained using both the consecutive desorption method and the dilution...

red mud (rm), a waste tailing from alumina production, (as an important environmental problem), can be used as a strong absorbent pollutant. in this study, the modified red mud (mrm) and pillared clay (pilc) were used for the removal of arsenate from water. the modified red mud (mrm) and pilc complex were characterized using xrd, sem and xrf microanalysis. the adsorption of arsenate on modified...

Unpublished AIChE shall not be responsible for statements or opinions contained in papers or printed in its publications. Abstract This paper describes a novel calorimeter applicable for the simultaneous measurement of adsorption isotherms and the corresponding heats of adsorption. The calorimeter is based on a new metrological principle as a gas surrounding the adsorption vessel containing the...

In this study, the effect of preparation route of magnetic graphene oxide (mGO) on Reactive Black 5 (RB5) adsorption was investigated. The synthesis of mGO was achieved both with (i) impregnation method (mGOi nanoparticles), and (ii) co-precipitation (mGOp nanoparticles). After synthesis, the full characterization with various techniques (SEM, FTIR, XRD, DTA, DTG, VSM) was achieved revealing ma...