نتایج جستجو برای: adsorptive cathodic stripping voltammetry

تعداد نتایج: 17912  

2008
Olga Domínguez-Renedo M. Encarnación Burgoa Calvo M. Julia Arcos-Martínez

This paper describes a procedure that has been optimized for the determination of lamotrigine by Differential Pulse Adsorptive Stripping Voltammetry (DPAdSV) using carbon screen-printed electrodes (CSPE) and mercury coated carbon screen-printed electrodes. Selection of the experimental parameters was made using experimental design methodology. The detection limit found was 5.0 x 10-6 M and 2.0 ...

2009
G. O. El-Sayed

The behavior of chlordiazepoxide has been studied using dc-polarography at dropping mercury electrode (DME) and cyclic voltammetry at glassy carbon electrode (GCE). In Britton-Robinson buffers, the drug developed three reduction irreversible waves in acidic solutions, and only two waves in alkaline media. The adsorptive stripping voltammetric behavior of chlorodiazepoxide was studied at GCE, an...

Journal: :Chemosensors 2021

In this work, different electrodes were employed for the determination of Cr(VI) by cathodic square-wave voltammetry (SWV) technique and adsorptive stripping (SWAdSV) in combination with diethylenetriaminepentaacetic acid. Using SWV, a comparison analytical performance bare glassy carbon electrode (GCE), ex situ (antimony-film—SbFE, copper-film—CuFE, bismuth-film—BiFE), GCE modified new magneti...

2008
Mohammed A. Al-Omar Ali F. Al-ghamdi Ahmad H. Al-ghamdi

A sensitive and reliable stripping voltammetric method was developed to determine chlorotetracycline drug. This method is based on the adsorptive accumulation of the complex of this drug with Zn (II) at a hanging mercury drop electrode and then a negative sweep was initiated, which yield a well defined cathodic peak at – 928 mV versus Ag/AgCl reference electrode. To achieve high sensitivity, va...

Journal: :Combinatorial chemistry & high throughput screening 2011
Arnaldo Aguiar Castro Ricardo Queiroz Aucélio Nicolás Adrián Rey Eliane Monsores Miguel Percio Augusto Mardini Farias

This paper describes a stripping method for the determination of nevirapine at the submicromolar concentration levels. The method is based on controlled adsorptive accumulation of nevirapine at thin-film mercury electrode, followed by a linear cyclic scan voltammetry measurement of the surface species. Optimal experimental conditions include a 2.0 x 10(-3) mol L(-1) NaOH solution (supporting el...

2013
Arnaldo Aguiar Castro Ana Isa Perez Cordoves Percio Augusto Mardini Farias

This paper describes a stripping method for the determination of acyclovir at the submicromolar concentration level. This method is based on controlled adsorptive accumulation of acyclovir at thin-film mercury electrode, followed by a linear cyclic scan voltammetry measurement of the surface species. Optimal experimental conditions include a NaOH solution of 2.0 × 10(-3) mol L(-1) (supporting e...

2010
Fangquan Xia Xin Zhang Changli Zhou Danzi Sun Yanmin Dong Zhen Liu

A new method was developed for simultaneous determination of copper, lead, and cadmium, based on their voltammetric response at a carbon paste electrode modified with hexagonal mesoporous silica (HMS) immobilized quercetin (HMS-Qu/CPE). Compared with quercetin modified carbon paste electrode (Qu/CPE) and quercetin ionic liquid modified carbon paste electrode (Qu-IL/CPE), the HMS-Qu/CPE exhibite...

2012
Pavla Macikova Vladimir Halouzka Jan Hrbac Petr Bartak Jana Skopalova

The performances of ionic liquid (1-hexyl-3-methylimidazolium-bis(trifluoromethylsulfonyl)imide, IL/CPE) and iron phthalocyanine (IP/CPE) modified carbon paste electrodes in electroanalytical determinations of rutin were evaluated and compared to the performance of unmodified carbon paste electrode (CPE). Cyclic voltammetry (CV), differential pulse voltammetry (DPV), differential pulse adsorpti...

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