It is sometimes profitable to measure the longitudinal nuclear spin polarization of He. The method described here takes advantage of the vaporized alkali metal already present in a glass target cell. Long range and short range interactions with polarized He gas result in an “effective” magnetic field felt by the alkali metal atoms. A precisely detectable Zeeman shift in the alkali EPR frequency...

Metal hydride electrodes have shown to be useful both in secondary batteries, e.g. the Ni/metal hydride system, and more recently in fuel cells, especially for direct borohydride fuel cells. This work provides in situ X-ray diffraction (XRD) results aiming at characterizing the phase transitions of the LaNi4.7Sn0.2Cu0.1 metal hydride alloy with and without Pt in the particle surface when charge...

Objective: The aims of this study were to investigate the release of element from, and the biological response in vitro to, cobalt-chromium alloys and other base-metal alloys used for the fabrication of metal-ceramic restorations. Material and methods: Eighteen different alloys were investigated. Nine cobalt-chromium alloys, three nickel-chromium alloys, two cobalt-chromium-iron alloys, one pal...

There are several benefits in using adhesive technique in removable prosthodontics as well as fixed prosthodontics. Previous studies have examined denture-base surface treatments that improve bond strength between a denture base resin and autopolymerizing repair resin. Dichloromethane and ethyl acetate are organic solvents that swell the denture base surface, thereby permitting diffusion of the...

D6056 prefabricated abutment includes placement D6057 custom abutment includes placement D6058 abutment supported porcelain/ceramic crown D6059 abutment supported porcelain fused to metal crown (high noble metal) D6060 abutment supported porcelain fused to metal crown (predominantly base metal) D6061 abutment supported porcelain fused to metal crown (noble metal) D6062 abutment supported cast m...

The iron-molybdenum cofactor of nitrogenase has unprecedented coordination chemistry, including a high-spin iron cluster called the iron-molybdenum cofactor (FeMoco). Thus, understanding the mechanism of nitrogenase challenges coordination chemists to understand the fundamental N2 chemistry of high-spin iron sites. This Account summarizes a series of studies in which we have synthesized a numbe...

The complexation of alkali metal ions with amphiphilic fullerene derivatives has been investigated by matrix-assisted laser desorption/ionization (MALDI) time-of-flight (TOF) mass spectrometry. The formation of analyte ions occurs via two competing mechanisms including electron transfer from matrix-derived ions and metal ion attachment. The interplay of these processes has been examined by lase...

We use a phase-changing metal alloy to reversibly tune the elastic rigidity of an elastomer composite. The elastomer is embedded with a sheet of low-melting-point Field’s metal and an electric Joule heater composed of a serpentine channel of liquid-phase gallium–indium–tin (Galinstan R ) alloy. At room temperature, the embedded Field’s metal is solid and the composite remains elastically rigid....