The synthesis and full characterization of novel 1,1′-difunctionalized ferrocene metalloligands is described. While one cyclopentadienyl ring has been functionalized with 2,2′-bipyridine for secondary coordination, the second Cp decorated different aryl moieties containing electron withdrawing groups such as 4-(CF3)C6H4 (2A) 3,5-(CF3)2C6H3 (2B) or 4-(NO2)C6H4 (2C). newly developed were reacted ...

Hydrogenolysis via targeted depolymerization of C–O linkages is a techno-economic beneficial process for converting lignin into highly valuable chemicals and clean fuels. In this work, macroporous silicalite-1 (S-1) array-supported Ru-Ni metallic phosphide composite (Ru-Ni12P5/S-15) was prepared as catalyst hydrogenolysis activity under relative mild conditions investigated using series compoun...

This study compared oxidative delignification of birch kraft pulp fibers to from acid hydrotropic fractionation (AHF) using p-toluenesulfonic (p-TsOH). Under oxygen at 20% consistency, AHF pulps with lower hemicellulose content showed higher than similar lignin despite its residual (cellulosic enzymatic lignin, CEL) being less reactive fewer ?-O-4 ether aryl linkages based on 2D13C-1H nuclear m...

Ein Ethylenglykol-dekorierter [6]Cyclo-meta-phenylen(CMP)-Makrozyklus wurde hergestellt und als Untereinheit für den Aufbau eines vierfachen AuI2−Aryl-Metallazyklus mit einer quadratischen Überstruktur genutzt. Die Ecken bestehen aus dinuklearen Gold(I)-Komplexen, von denen bisher nur dreieckige Metallazyklen bekannt waren. Das Zusammenspiel flexibler Konformation des [6]CMP-Makrozyklus der sta...

relations and friends. Conversely, insane conduct may be properly testified by a relation, but fail to be displayed when under observation in an institution. The medical evidence then will probably be that of mental deficiency. In such case the witness must balance the relative merits of hearsay statements and personal observation. Mental defect mnay be simulated by mental dullness resulting fr...