Direct sulfonation of methane with SO3 to methanesulfonic acid (MSA) is accomplished in sulfuric acid with almost 100% selectivity in the presence of a catalyst, namely, Ce and Rh salts and molecular oxygen as the catalyst regenerator. In the absence of O2, the catalyst remains effective but the selectivity to MSA decreases to 53% and byproducts, principally CH3OSO3H, are formed. The effects of...

Passive signal regeneration based on the Membrane InP Switch (MIPS) is demonstrated. Because of the high confinement of light in the active region of the MIPS, the device acts as a saturable absorber with a highly non-linear response. Using this effect, the extinction ratio (ER) of low-ER signals can be tripled and a receiver sensitivity enhancement of 4.5dB is demonstrated using an input signa...

Air may be dehumidified when it is brought into contact with a suitable liquid desiccant. Different types of liquid desiccants are available in the market and the application of the proper desiccant in hot humid climates would improve the dehumidification effectiveness. The driving potential for a dehumidification process is the difference in the pressure of the water vapor in the air and the w...

biofiltration of triethylamine (tea) vapor used as a catalyst in casting operations was evaluated in this study. the unit consisted of a 6-l three-stage biofilter containing a mixture of compost and wood chips (40:60 v/v) as the filter medium. seed microbial population from municipal activated sludge was acclimated for a period of three weeks prior to the actual experimental runs. in the startu...

tetrahydropyranylation of alcohols and phenols, acetylation of aldehydes and n-boc protection of amines are efficiently catalyzed by melamine trisulfonic acid (mtsa). all reactions were performed at room temperature in good to high yields.

The imine podands tris[(2-nitrobenzylidene)aminoethyl]amine and tris[(2-nitrobenzylidene)aminopropyl]amine both stabilize copper(I), forming {tris[(2-nitrobenzylidene)aminoethyl]amine-kappa4N}copper(I) perchlorate acetonitrile disolvate, [Cu(C27H27N7O6)]ClO4.2CH3CN, (II), and {tris[(2-nitrobenzylidene)aminopropyl]amine-kappa4N}copper(I) perchlorate, [Cu(C30H33N7O6)]ClO4, (VI), respectively. The...