The reaction of a manganese(V)-oxo porphyrinoid complex with the Lewis acid B(C6F5)3 leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C6F5)3, reacts with ArO-H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(V)(O) starting material.

R. Adami, H. Aro, E.Järvenpää, K. Könkö, V. Hietaniemi, E. Reverchon, R.Huopalahti Department of Biochemistry & Food Chemistry University of Turku, FIN-20014 Turku, Finland, E-mail: [email protected] # MTT Agrifood Research Finland, Chemistry Laboratory, FIN-31600 Jokioinen, Finland Department of Chemical and Food Engineering University of Salerno, Via Ponte Don Melillo, 84084, Fisciano, Italy E-...

Abstract Variations in the water vapor that atmospheric rivers (ARs) carry toward North America within Pacific storms strongly modulates spatiotemporal distribution of west‐coast precipitation. The “AR Recon” program was established to improve forecasts landfalling Pacific‐coast ARs and their associated Dropsondes are deployed from weather reconnaissance aircraft pressure sensors have been adde...

AIM To study the changes of cell cycle, mitochondrial membrane potential and caspase activation in response to an antitumour drug Taxol in ARO and KTC-2 cell lines of anaplastic thyroid carcinoma. METHODS Experiments were done on thyroid anaplastic cancer cell lines ARO and KTC-2 using Western blotting, flow cytometry, light and fluorescent microscopy. RESULTS Taxol significantly activated ...

Penelitian ini bertujuan untuk menganalisa tambahan penghasilan pegawai, lingkungan kerja dan motivasi terhadap kinerja pegawai negeri sipil dengan kepuasan sebagai variabel intervening pada Rumah Sakit Umum Daerah Aro Suka Kabupaten Solok. Jenis penelitian menggunakan pendekatan kuantitatif metode Structural Equation Modeling (SEM). Teknik pengumpulan data kuesioner. Responden adalah 98 orang ...

In the load balancing problem, there is a set of servers, and jobs arrive sequentially. Each job can be run on some subset of the servers, and must be assigned to one of them in an online fashion. Traditionally, the assignment of jobs to servers is measured by the L1 norm; in other words, an assignment of jobs to servers is quanti ed by the maximum load assigned to any server. In this measure t...

• Data-driven ARO is firstly applied in industrial multi-type energy systems optimization under uncertainty. The data-driven uncertainty set formed by RKDE based on the big data. Deterministic and are formulated as MINLP problems. effect of parameters solution explored. operational great significance for improving overall efficiency processes. Facing new challenges brought widespread uncertaint...

The ML-PMHT MultistaticTracker for SharplyManeuvering Targets Report Title The maximum likelihood probabilistic multi-hypothesis tracker (ML-PMHT) is applied to a benchmark multistatic active sonar scenario with multiple targets, multiple sources, and multiple receivers. We first compare the performance of the tracker on this scenario when it is applied in Cartesian measurement space, a typical...