A recently developed atomistic method capable of calculating the fragile (non-Arrhenius) temperature behavior of highly viscous liquids is further tested by studying a model of SiO(2), a glass former well known for its Arrhenius temperature behavior (strong). The method predicts an Arrhenius temperature variation, in agreement with experiments, the origin of which is revealed by both quantitati...

Several extracellular enzymes that are responsible for plant tissue maceration were detected in culture supernatant of the psychrotrophic bacterium Chryseomonas luteola MFCL0. Isoelectrofocusing experiments showed that pectate lyase (PL) activity resulted from the cumulative action of three major isoenzymes, designated PLI, PLII, and PLIII. Cellulolytic activity was also detected in culture sup...

The dielectric spectra of most simple liquids are characterized by two relaxation processes: (i) the alpha-process, an intense, broad non-Debye relaxation with a non-Arrhenius temperature dependence and (ii) a beta process, evident mainly below the glass transition and having nearly Arrhenius temperature behavior. However, the dielectric spectra of monoalcohols show three processes: two that re...

The electrical conductivity of LiCl-GdCl3 molten systems with the gadolinium chloride additions ranging from 0 to 23 mol% was measured depending on both temperature and concentration GdCl3. molar GdCl3-LiCl system is calculated taking into account assumption additivity volume mixture. obtained dependencies can be approximated by Arrhenius-type equation. effective activation energy Ea increased ...

It is becoming common practice to partition glass-forming liquids into two classes based on the dependence of the shear viscosity η on temperature T. In an Arrhenius plot, ln η vs 1/T, a strong liquid shows linear behavior whereas a fragile liquid exhibits an upward curvature [super-Arrhenius (SA) behavior], a situation customarily described by using the Vogel-Fulcher-Tammann law. Here we analy...

Inversion of sucrose by bakers' yeast follows the same course as inversion catalyzed by yeast invertase. Rate of inversion increases exponentially with temperature; the temperature characteristic in the Arrhenius equation is 10,700 below 13-17 degrees C., and 8,300 above that temperature. Temperature inactivation occurs above 40 degrees C. The effects of temperature upon rate of inversion were ...

Extensive isothermal-isobaric ~NPT! molecular dynamics simulations at many different temperatures and pressures have been carried out in the well-known Kob–Andersen binary mixture model to monitor the effect of pressure ~P! and temperature ~T! on the dynamic properties such as the viscosity (h) and the self-diffusion (Di) coefficients of the binary system. The following results have been obtain...

The removal of radionuclides from the primary coolant system nuclear power plants occurs with dissolution corrosion metal oxide layers deposited radionuclides. Kinetic experiments were conducted a synthetic magnetite specimen in form thin plate using an aqueous solution oxalic acid as reducing agent. effects concentration and temperature investigated on kinetics reductive specimen. In particula...

The stress-strain data of 20MnNiMo alloy were collected from a series of hot compressions on Gleeble-1500 thermal-mechanical simulator in the temperature range of 1173 ∼ 1473 K and strain rate range of 0.01 ∼ 10 s(-1). Based on the experimental data, the improved Arrhenius-type constitutive model and the artificial neural network (ANN) model were established to predict the high temperature flow...

On decreasing the temperature T , supercooled water and other tetrahedral network-forming liquids, such as BeF2 or SiO2, appear to display a dynamic crossover from non-Arrhenius dynamics (with T -dependent activation energy) to Arrhenius dynamics (with constant activation energy). Simulations for water models show that this crossover occurs on crossing the Widom line TW (P ), the locus of maxim...