Human alpha defensins are a class of antimicrobial peptides with additional antiviral activity. Such antimicrobial peptides constitute a major part of mammalian innate immunity. Alpha defensins contain six cysteines, which form three well defined disulfide bridges under oxidizing conditions. Residues C3-C31, C5-C20, and C10-C30 form disulfide pairs in the native structure of the peptide. The ma...

Difenacoum, an antivitamin K anticoagulant, has been widely used as rodenticide to manage populations of rodents. Difenacoum belongs to the second generation of anticoagulant, and, as all the molecules belonging to the second generation of anticoagulant, difenacoum is often involved in primary poisonings of domestic animals and secondary poisonings of wildlife by feeding contaminated rodents. T...

Nonylphenol belongs to the most investigated xenohormones acting at the estrogen receptor. Technical nonylphenol contains approximately 20 para-substituted isomers. Because of limitations in testing and quantifying all 20 isomers in the mixture, the linear form, 4n-NP, is often used as a reference substance, even though it is not present in the technical mixture. Here, we report on the synthesi...

An experiment was conducted to determine fatty acid (FA) pro?les in Chinese Maiwa yak milk across the lactation cycle. Sixty-one healthy, similar weight, 4-7 years old, 3-6 parity yaks with unrelated background were selected randomly from Hongyuan County, Sichuan province, southwest of China (with altitude over 3500 m). The graze on natural pasture all year around without irrigation, fertilizer...

Metoksimetiltrifenilfosfonyum klorür (MOMTPPC) tek kristalleri Elektron Paramanyetik Rezonans (EPR) spektroskopi yöntemi ile analiz edilmiştir. MOMTPPC kristalleri, 60Co- kaynağı ışınlanarak paramanyetik bozukluklar oluşturulmuştur. kristallerinin EPR spektrumları, 120 K sıcaklıkta üç dik eksen etrafında belirli açılarda döndürülerek spektrumları alınmıştır. MOMTPPC'de ışınlama etkisiyle oluşa...

the aim followed in this study was to make a comparison of the composition of fatty acids available in the sperm lipids of cattle, sheep and goat. semen samples were collected from 28 holestein cows, 12 chal rams and 7 mahabadi goats. after washing out and removal of the seminal plasma, total lipids of the sperm were extracted and fatty acids trans-methylated. the fatty acid methyl esters were ...

For the first time, relative distributions of optical and geometrical isomers in selected propylene glycol acetals are determined. Resolution of the four acetal isomers possible through the reaction of racemic propylene glycol (PG) with selected aldehydes is demonstrated. The four isomers are ascribed to the presence of syn and anti geometrical isomers for each optically active PG acetal enanti...

Saturated concrete is significantly different from dry in fracture mechanical properties. Using the wedge-splitting tensile method to research rule of change moisture content, double-K toughness and energy three strength grades (C20, C30, C40) immersed a free water environment for 0 h, 2 5 24 120 h were studied order provide support safety evaluation structures environment. The initial cracking...

The effect of molecular vibrations on electronic transport is investigated with the smallest fullerene C20 bridge, utilizing the Keldysh nonequilibrium Green's function techniques combined with the tight-binding molecular-dynamics method. Large discontinuous steps appear in the differential conductance when the applied bias voltage matches particular vibrational energies. The magnitude of the s...

Self-metathesis of undecenoic acid with [(PCy3)2Cl2Ru=CHPh] (2), followed by exhaustive hydrogenation yielded pure 1,20-eicosanedioic acid (5) (>99%) free of side-products from isomerization. Polycondensation with eicosane-1,20-diol (6), formed by reduction of the diol, yielded polyester 20,20 (Tm = 108 °C). By comparison, the known ADMET polymerization of undec-10-enyl undec-10-enoate (7), and...