In the present study, the performance of chitosan coated carbon was evaluated for the removal of chromium (VI) and cadmium (II) from its aqueous solution. The chitosan coated carbon was prepared and characterized by using the various analytical tools such as FTIR, TGA, DSC and XRD. Batch adsorption experiments were performed in order to examine the effects of initial concentration, pH, and adso...

The extraction of cellulose from sisal fiber was done initially using the steam explosion method. Extracted cellulose was grafted with acrylic acid in the presence of ceric ammonium nitrate redox initiator. The grafting phenomenon taking place between cellulose and the acrylic acid was proved by Fourier transform infrared spectroscopy (FTIR). The prepared graft copolymer was used as adsorbent f...

Cation adsorption data using MnCl2 and the proton isotherm of a Si oxide were compared with pH as the variable. The cation adsorption data quantitatively correlated with the proton isotherm analysis; the H+/Mn* exchange ratio was 6.0. The presence of adsorption plateaus are due to pH-dependent (step) reactions; this was suggested as the only reasonable explanation for adsorption isotherms cover...

This study examined the interactions of MoO4(2-) + SO4(2-), MoO4(2-) + SeO4(2-), and MoO4(2-) + SeO3(2-) systems on gamma-Al2O3 to better understand the competitive adsorption of these anions in the natural environment. The Freundlich isotherms of anionic adsorption onto gamma-Al2O3 in single and binary solutes were also investigated to estimate the competition between these anions. Experimenta...

Separation of Pb2+ from Cu2+-Pb2+ mixed solution by a newly-developed ion separating agent was examined, which was obtained by clothing chitin whiskers (ChW) on the surface of potassium tetratitanate whiskers (PTW). The separation capability and mechanism of the ion separating agent (ChW-PTW) was determined, based on the difference of the adsorption isotherm pattern and the adsorption kinetics ...

In this paper, the sorption characteristics of aniline on Cr-bentonite prepared using synthetic wastewater containing chromium was investigated in a batch system at 30 degrees C. The effects of relevant parameters, such as pH value of solution, adsorbent dosage and initial aniline concentration were examined. The experimental data were analyzed by the Langmuir and Freundlich, and Temkin models ...

Agricultural solid waste (corn cob) has been investigated asbiosorbent for removal of metribuzin herbicide from aqueous solution. Parameters influencing extraction efficiency such as pH of the sample, contact time of sample with biosorbent, shaking time, temperature, heating time, sorbent dose were studied. Maximum sorption of metribuzinwas found at pH 5.0. The sorption of metribuzin on corn co...

Rhodamine B (Rh B) is a toxic dye that is harmful to the environment, humans, and animals, and thus the discharge of Rh B wastewater has become a critical concern. In the present study, reduced graphene oxide-supported nanoscale zero-valent iron (nZVI/rGO) was used to treat Rh B aqueous solutions. The nZVI/rGO composites were synthesized with the chemical deposition method and were characterize...

A fundamental study on the adsorption of metal elements on Shirasu, a pyroclastic flow deposit distributed in southern Kyushu, Japan, has been conducted. The adsorption experiment was carried out by a batch method, and by using Zn(II) and Cu(II) under several conditions; the effects of the initial concentration of metal ions, grain size, and pH were investigated. At smaller grain sizes, the amo...

Reaction of Cr(CO)(6) with trimesic acid in DMF affords the metal-organic framework Cr(3)(BTC)(2).nDMF (BTC(3-) = 1,3,5-benzenetricarboxylate), which is isostructural to Cu(3)(BTC)(2).3H(2)O. Exchanging DMF for methanol and heating at 160 degrees C under dynamic vacuum for 48 h results in the desolvated framework Cr(3)(BTC)(2). Nitrogen gas adsorption measurements performed at 77 K revealed a t...