The article describes the synthesis and properties of α-((4-cyanobenzoyl)oxy)-ω-methyl poly(ethylene glycol), the first poly(ethylene glycol) stabilizer for metal nanoparticles that is based on a cyano rather than a thiol or thiolate anchor group. The silver particles used to evaluate the effectiveness of the new stabilizer typically have a bimodal size distribution with hydrodynamic diameters ...

The aqueous mixtures of light gas molecules under low-temperature and high-pressure conditions are candidates to form gas hydrate clathrates. The formation of gas hydrate may lead to various problems and extra charges in natural gas production and processing. The presence of hydrate crystals forming a stable solid phase can potentially block the wells, pipes, and process facilities. To avoid su...

Poly(ethylene glycol) (PEG)-armed Ru(II)-bearing microgel-core star polymer catalysts were used for the transfer hydrogenation of ketones. The star catalysts (Ru(II)-PEG Star) were one-pot synthesized by ruthenium-catalyzed living radical polymerization of poly(ethylene glycol) methyl ether methacrylate (PEGMA) and a sequential linking reaction with ethylene glycol dimethacrylate (1) and diphen...

Plasmodium berghei-infected mouse red cells have enhanced fusion capacity as triggered by addition of poly(ethylene glycol) in the presence of Ca2+. The uptake of Ca2+ in P. berghei-infected cells is greater than in normal cells, and the difference in Ca2+ uptake was found to be enhanced in the presence of poly(ethylene glycol). Fusion of normal and P. berghei-infected red cells by poly(ethylen...

Dense flat-sheet membranes were prepared from poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) using the casting solvents chloroform and 1,1,2-trichloroethylene. X-ray diffraction, tapping mode atomic force microscopy (TM-AFM), and contact angle studies were used to characterize the membranes. The surface energy and the solubility parameters of the PPO membranes were determined from the measured co...

Dimethoxycurcumin (DMC) is an analog of curcumin with superior efficacy in various disease models. Currently, drug delivery system research on DMC is very limited, and it has become a huge challenge to realize further developments and clinical applications. In the present study, a kind of amphiphilic block copolymer, N-t-butoxycarbonyl-phenylalanine terminated monomethoxyl poly (ethylene glycol...

Sodium hypochlorite was an excellent disinfectant at low temperatures. With the addition of ethylene glycol to prevent freezing, hypochlorite solutions at low free available chlorine concentrations, were effective against Bacillus subtilis var. niger spores from 0 to -40 C. The effectiveness of this decontaminant was influenced by temperature, pH, and concentration, with pH 7.2 the optimum for ...

The molar activity of crystalline mitochondrial aspartate aminotransferase is decreased to 10% of that of the enzyme in solution. The activity was measured in suspensions of non-cross-linked microcrystals (average dimensions 22 microns X 5 microns X 0.8 microns) in 30% (w/v) poly(ethylene glycol). Kinetic tests ruled out the possibility that diffusion of the substrate in the crystals is rate-li...

Diabetes is a serious chronic disease, which globally affects more than 400 million patients. Beta cell therapy has potential to serve as an effective cure type 1 diabetes and several studies have already shown promising results in this regard. One of the major obstacles therapy, however, hypoxic environment that therapeutic cells are subjected immediately after transplantation. In study, new a...