We present an approach for calculating nonlinear spectroscopic observables, which overcomes the approximations inherent to current phenomenological models without requiring the computational cost of performing molecular dynamics simulations. The trajectory mapping method uses the semi-classical approximation to linear and nonlinear response functions, and calculates spectra from trajectories of...

We report a photodetachment and high-resolution photoelectron imaging study of cold 2-hydroxyphenoxide anion, o - HO(C6H4)O(-), cooled in a cryogenic ion trap. Photodetachment spectroscopy revealed a dipole-bound state (DBS) of the anion, 25 ± 5 cm(-1), below the detachment threshold of 18 784 ± 5 cm−1 (2.3289 ± 0.0006 eV), i.e., the electron affinity of the 2-hydroxyphenoxy radical o - HO(C6H4...

Dr. Bernard Anderson, associate professor of industry (vice-chairman) Alexander Capron, associate professor oflaw Andrew J. Condon, director ofstudent life Dr. Helen C. Davies, associate professor of microbiology (medicine) Dr. Richard S. Dunn, chairman and professor ofhistory Dr. Fred G. Kempin, chairman andprofessor ofbusiness law Dr. Phoebe S. Leboy, professor ofbiochemistry (dental medicine...

Correlated driving-and-dissipation equation (CODDE) is an optimized complete second-order quantum dissipation approach, which originally concerned with the reduced system dynamics only. However, one can actually extract hybridized bath from CODDE aid of dissipaton-equation-of-motion theory, a statistical quasi-particle formalism. Treated as one{dissipaton successfully extended to deal Herzberg-...