Transition-metal-based molecular complexes are a class of catalyst materials for electrochemical CO2 reduction to CO that can be rationally designed to deliver high catalytic performance. One common mechanistic feature of these electrocatalysts developed thus far is an electrogenerated reduced metal center associated with catalytic CO2 reduction. Here we report a heterogenized zinc-porphyrin co...

Solar-driven photocatalytic conversion of CO2 into fuels has attracted a lot of interest; however, developing active catalysts that can selectively convert CO2 to fuels with desirable reaction products remains a grand challenge. For instance, complete suppression of the competing H2 evolution during photocatalytic CO2-to-CO conversion has not been achieved before. We design and synthesize a spo...

The Prairie Heating and CO2 Enrichment (PHACE) experiment has been initiated at a site in southern Wyoming (USA) to simulate the impact of warming and elevated atmospheric CO2 on ecosystem dynamics for semiarid grassland ecosystems. The DAYCENT ecosystem model was parametrized to simulate the impact of elevated CO2 at the open-top chamber (OTC) experiment in north-eastern Colorado (1996-2001), ...

The recent development of tight oil reservoirs has led to an increase in oil production in the past several years due to the progress in horizontal drilling and hydraulic fracturing. However, the expected oil recovery factor from these reservoirs is still very low. CO2-based enhanced oil recovery is a suitable solution to improve the recovery. One challenge of the estimation of the recovery is ...

Deep saline aquifers are one of the most suitable geologic formations for carbon sequestration. The linear and global stability analysis of the time-dependent density-driven convection in deep saline aquifers is presented for long-term storage of carbon dioxide (CO2). The convective mixing that can greatly accelerate the CO2 dissolution into saline aquifers arises because the density of brine i...

AIM The aim of this study was to investigate if an initial ETCO2 value at or below 1.3 kPa can be used as a cut-off value for whether return of spontaneous circulation during pre-hospital cardio-pulmonary resuscitation is achievable or not. MATERIALS AND METHODS We prospectively registered data according to the Utstein-style template for reporting data from pre-hospital advanced airway manage...

In this work, our objective was to examine methods for processing cashew nut shell liquid and cashew shell with carbon dioxide and water. Supercritical CO2 was applied for extraction of split cashew shells and near-critical water was applied for reaction of the cashew shell material. In the extractions, it was found that a pressurization-depressurization step that was approximately 1 h gave ext...

Almost 20 years ago, the first CO2 capture and storage (CCS) project began injecting CO2 into a deep geological formation in an offshore aquifer. Relevant science has advanced in areas such as chemical engineering, geophysics, and social psychology. Governments have generously funded demonstrations. As a result, a handful of industrial-scale CCS projects are currently injecting about 15 megaton...

With recent observations of diminishing summer Arctic sea ice extent, the hypothesis of a “tipping point” in summer ice cover has been the focus of a number of studies. This view suggests that as summer Arctic sea ice cover retreats it will reach a critical point after which the ice–albedo effect will cause the summer ice cover to disappear altogether. We have examined the heuristic argument be...

When CO2 is injected in saline aquifers, dissolution causes a local increase in brine density that can cause Rayleigh-Taylor-type gravitational instabilities. Depending on the Rayleigh number, density-driven flow may mix dissolved CO2 throughout the aquifer at fast advective time-scales through convective mixing. Heterogeneity can impact density-driven flow to different degrees. Zones with low ...