Capillary electrophoresis is used to separate ultrasmall ( approximately 1 nm) carboxylate functionalized Si nanoparticles (Si-np-COO(-)) prepared via hydrosilylation with an omega-ester 1-alkene. The electropherograms show a monodisperse Si core size with one or two carboxylate groups added to the surface. On-column detection of their laser-induced fluorescence demonstrates that the individual...

1. I n t r o d u c t i o n 1. Let M be a real-analytic manifold, Vect M the Lie algebra of analytic vector fields on M. We consider a vector field f E Vect M as a differential operator of first order on the algebra of smooth functions C ~ (M) which satisfies the differentiation rule f(W1W2) -" (fw1)W2 + wI(fW2) VWI, W2 E Coo(M). A point z E M will be identified with the corresponding homomorphi...

Estuarine and marine sediments are a probable end point for many engineered nanoparticles (ENPs) due to enhanced aggregation and sedimentation in marine waters, as well as uptake and deposition by suspension-feeding organisms on the seafloor. Benthic infaunal organisms living in sediments encounter relatively high concentrations of pollutants and may also suffer toxic effects of ENPs. We tested...

The relation between catalytic reactivities and metal/metal oxide ratios, as well the functions of metal oxides were investigated in CO2 hydrogenation reaction over highly active Cox(CoO)1–x catalysts operando. reactivity samples methanation improves with increased CoO concentration. Strikingly, sample highest concentration CoO, i.e., Co0.2(CoO)0.8, shows activity at temperatures lower than 200...

objective(s): this study focused on determining cytotoxic effects of copper oxide nanoparticles (cuo nps) on chronic myeloid leukemia (cml) k562 cell line in a cell-specific manner and its possible mechanism of cell death. we investigated the cytotoxicity of cuo nps against k562 cell line (cancerous cell) and peripheral blood mononuclear cell (normal cell). materials and methods: the toxicity w...

This study focuses on the leadership structure at the very top of a firm. Specifically, it examines how the presence of a COO/president, who is separate from the CEO, affects strategic change and CEO dismissal. With longitudinal data on the tenures of 207 CEOs, results suggest that the presence of a separate COO/president increases the magnitude of strategic change under conditions of low firm ...

Convenient determination of glucose in a sensitive, reliable and cost-effective way has aroused sustained research passion, bringing along assiduous investigation of high-performance electroactive nanomaterials to build enzymeless sensors. In addition to the intrinsic electrocatalytic capability of the sensing materials, electrode architecture at the microscale is also crucial for fully enhanci...

Nanoparticle (NPs) containing essential metals are being considered in formulations of fertilizers to boost plant nutrition in soils with low metal bioavailability. This paper addresses whether colonization of wheat roots by the bacterium, Pseudomonas chlororaphis O6 (PcO6), protected roots from the reduced elongation caused by CuO NPs. There was a trend for slightly elongated roots when seedli...

The reduction of CuO dispersed on ̄uorite-type oxide catalysts, namely La-doped CeO2 and Y-doped ZrO2 was studied in this work. On both supports distinct copper species were identi®ed as a function of copper content by temperatureprogrammed reduction (TPR) by H2 and CH4, X-ray photoelectron spectroscopy (XPS), X-ray powder diffraction (XRD) and scanning transmission electron microscopy/energy d...