Nanocrystallized ceria-based coatings were prepared on TA6V titanium alloy by using a three-step procedure: substrate pretreatment, electrochemical impregnation and final heat treatment. UV–vis and Raman in situ spectroscopies performed at the substrate interface during the electrochemical impregnation, showed experimentally for the first time that the interfacial deposit is made up of cerium h...

In this study, the effect of dry oxidation on the electrochemical properties of carbon nanotube arrays is investigated. Oxygenated surface functional groups were introduced to the arrays by oxygen plasma treatment, where their surface concentrations were varied by controlling the exposure time. The finding presented herein shows an augmentation of nearly thirty times in term of specific capacit...

Traditional vanadium batteries use pure sulfuric acid as electrolyte, but H2SO4 does not absorb enough vanadium ions to make the electrolyte an efficient energy source. This study investigates the effect of hydroxylation process on electrochemical and operational properties of carbon felt electrode in VOSO4 solution with an optimized supporting electrolyte (a mixture of six parts HCl and 2.5 pa...

The electrooxidation of aqueous solutions containing 5mM of o-, m- and p-cresol at pH 4.0 has been investigated using a flow filter-press reactor with a boron-doped diamond (BDD) under galvanostatic electrolysis. All cresols are degraded at similar rate up to attaining overall mineralization. Comparable treatment of the m-cresol effluent on PbO(2) leads to partial electrochemical incineration. ...

the aisi 316 l stainless steel (ss) specimens were exposed to passivation surface through two different processes including; holding in 40-vol% hno3 at temperature of 60 ºc for 30 min and 15-vol%h2so4 at ambient temperature for 1 hour. the corrosion behavior of specimens was evaluated in physiological solutions by electrochemical in vitro tests through linear and tafel polarization tests. cycli...

Electrochemical reactions in the electrochemical treatment of tumors (EChT) induce extreme pH changes and, consequently, protein electrodenaturation fronts intimately related to tumor destruction. Here we introduce a new in vitro EChT collagen–macronutrient gel (CMG) model to study protein electrodenaturation fronts as a mean of assessing EChT effectiveness. Our CMGmodel shows that from an init...

We have developed a wastewater treatment system that incorporates an electrolysis cell for on-site wastewater treatment coupled with molecular hydrogen production for use in a hydrogen fuel cell. Herein, we report on the efficacy of a laboratory-scale wastewater electrolysis cell (WEC) using real human waste for the first time with semiconductor electrode utilizing a mixed particle coating of b...

Treatment of nitrate contaminated water which is unsuitable for biological removal using an electrochemical method with Fe as a cathode and Ti/IrO(2)-Pt as an anode in an undivided cell was studied. In the absence and presence of 0.50 g/L NaCl, the nitrate-N decreased from 100.0 to 7.2 and 12.9 mg/L in 180 min, respectively, and no ammonia and nitrite by-products were detected in the presence o...

Electrochemical treatment, specified as electrochemical chloride extraction (ECE), is one of the common techniques developed for rehabilitation chloride-contaminated reinforced concrete. In practice, ECE time-consuming; instance, treatment duration could last several weeks or even longer. order to reduce laboratory work, this paper presents some results about a numerical study ECE. It solve ser...