Previous work (1) showed t,hat when the concentration of plasma proteins is reduced by plasmapheresis, the concentration of serum protein varied inversely with the chloride and directly with the calcium, while no relation could be demonstrated between protein and total base or bicarbonat,e. The experiments were open to the serious object,ion that plasmapheresis involves the injection of a solut...

Kornyshev [A.A. Kornyshev, J. Phys. Chem. B 111 (2007) 5545] has recently modelled the (metal)/(ionic liquid) junction and predicted therefrom the capacitance of that interface as a function of the applied potential. One of the purposes of the present article is to demonstrate that, at least in one particular case, the same prediction can be made more simply by applying the principles that Gouy...

We present a simulation scheme based on the lattice-Boltzmann method to simulate the dynamics of charged colloids in an electrolyte. In our model we describe the electrostatics on the level of a Poisson-Boltzmann equation and the hydrodynamics of the fluid by the linearized Navier-Stokes equations. We verify our simulation scheme by means of a Chapman-Enskog expansion. Our method is applied to ...

Different types of charge storage mechanisms at unmodified graphite vs. glassy carbon electrodes in acid sulphate supporting solution containing potassium hexacyanoferrate (II) redox active electrolyte, have been revealed by electrochemical impedance spectroscopy and supported by cyclic voltammetry experiments. Reversible charge transfer of Fe(CN)6 redox reaction detected by assessment of CVs o...

A commercial system for surface plasmon resonance (SPR) possessing a batch-type flow channel has been simply modified so as to conduct in situ SPR measurements under polarization of an Au sensor chip at constant potentials. The modified instrument can monitor electrochemical reactions of monolayer materials with high stability and high reproducibility. The redox reaction of a self-assembled mon...

1. A double-lumen perfusion technique was used to study the effect of a wide range of concentrations of the dipeptide glycyl-L-alanine and its constituent amino acids on water and electrolyte absorption from iso-osmotic solutions in the upper jejunum of normal human subjects. 2. There was no significant absorption of water and electrolytes from sodium chloride solution (150 mmol/l) but the pres...

Batch potentiometric titration analyses were made on a 7-Al,O, colloidal suspension and interpreted in terms of the electroneutrality principle. Three titration methods involving a singular reference curve were compared. The first reference used was theoretical, the latter two were representative supernatant curves: an electrolyte solution, and an aliquot of the zero point of titration (ZPT) su...

From previous experiments, it was determined that nickel was able to coat boron fiber, however this was done unevenly, with cracks characterizing the coating. This was where it was hypothesized that the boron fiber crossed the interface of the nickel electrolyte solution during electrodeposition. This was different than the coating at the middle, which was all under the electrolyte solution, an...

Supercapacitors are electrochemical energy-storage devices that exploit the electrostatic interaction between high-surface-area nanoporous electrodes and electrolyte ions. Insight into the molecular mechanisms at work inside supercapacitor carbon electrodes is obtained with (13)C and (11)B ex situ magic-angle spinning nuclear magnetic resonance (MAS-NMR). In activated carbons soaked with an ele...

The instability of currently used electrolyte solutions and of the carbon support during charge-discharge in non-aqueous lithium-oxygen cells can lead to discharge products other than the desired Li2O2, such as Li2CO3, which is believed to reduce cycle-life. Similarly, discharge in an O2 atmosphere which contains H2O and CO2 impurities would lead to LiOH and Li2CO3 discharge products. In this w...