نتایج جستجو برای: electronic spectroscopy
تعداد نتایج: 386596 فیلتر نتایج به سال:
The best determination of the most stable protonation site in aromatic molecules relies nowadays on the IR spectroscopy and ab initio calculations. It appears that these methods are not necessarily unambiguous and cannot always be safely employed. We present in this paper an example showing that electronic spectroscopy of cold ions complemented with ab initio calculations gives clear results on...
We present here the first room-temperature 2D electronic spectroscopy study of energy transfer in the plant light-harvesting complex II, LHCII. Two-dimensional electronic spectroscopy has been used to study energy transfer dynamics in LHCII trimers from the chlorophyll b Qy band to the chlorophyll a Qy band. Observing cross-peak regions corresponding to couplings between different excitonic sta...
The most general molecular dynamic processes involve the coupled flow of both valence electronic charge and vibrational energy. Time-Resolved Photoelectron Spectroscopy (TRPES) is a powerful probe of ultrafast non-adiabatic dynamics in polyatomic molecules, as it simultaneously observes both electronic and vibrational dynamics [1]. The most detailed information, however, obtains from observing ...
Doping of carbon nanotubes with nitrogen should provide more control over the nanocarbon electronic structure. In addition to the chemical and arc-discharge alternative methods used nowadays, we suggest ion irradiationas an alternative way to introduce N impurities into nanotubes. The impinging ions can directly occupy the sp2 positions in the nanotube atomic network. As an alternative way N ni...
The results of an investigation of the electronic structure of the valence band of various Al-based complex intermetallic alloys, carried out using the X-ray emission spectroscopy technique, are presented and discussed. It is shown that the electronic structure results from an interplay between covalency and repulsive interactions that contributes to the formation of a pseudo-gap at the Fermi l...
We describe a novel method for semiconductor laser noise reduction that uses a combination of optical and electronic feedback. A Doppler-free Faraday resonance in Cs vapor provided both optical feedback and discrimination for an electronic feedback scheme incorporating FM sideband spectroscopy. The introduction of electronic feedback further reduced the low-frequency fluctuation noise power by ...
The emergence of two-dimensional electronic materials has stimulated proposals of novel electronic and photonic devices based on the heterostructures of transition metal dichalcogenides. Here we report the determination of band offsets in the heterostructures of transition metal dichalcogenides by using microbeam X-ray photoelectron spectroscopy and scanning tunnelling microscopy/spectroscopy. ...
The unique catalytic activity of supported Au nanoparticles has been ascribed to various effects including thickness/shape, the metal oxidation state, and support effects. Previously, we reported the synthesis of ordered Au monolayers and bilayers on TiO(x), with the latter being significantly more active for CO oxidation than the former. In the present study, the electronic and chemical proper...
Coherent structural trapping through wave packet dispersion during photoinduced spin state switching
The description of ultrafast nonadiabatic chemical dynamics during molecular photo-transformations remains challenging because electronic and nuclear configurations impact each other and cannot be treated independently. Here we gain experimental insights, beyond the Born-Oppenheimer approximation, into the light-induced spin-state trapping dynamics of the prototypical [Fe(bpy)3]2+ compound by t...
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