Hydrogels based on N-isopropylacrylamide and sodium acrylate as ionic comonomer were synthesized by free radical polymerization in water using N,N'-methylenebisacrylamide as crosslinker and ammonium persulfate as initiator. The glass transition of dried copolymers poly(N-isopropylacrylamide) (PNIPA) and poly(sodium acrylate) (SA) gels and demixing/mixing transition of PNIPA-SA hydrogels swollen...

Acrylates are well recognized as allergens. People working in the graphic arts field are exposed to acrylate-based printing inks and are therefore at high risk for occupational allergic contact dermatitis to acrylates. The most commonly used acrylic monomers in the printing process are 2-hydroxyethyl acrylate, 2-hydroxypropyl acrylate, 2hydroxypropyl methacrylate, 2-hydroxyethyl methacrylate, a...

The aim of the present study was to combat wood decay based on the approach controlled-release biocides from polymers. The possibility of introducing polymer-bonded fungicides into the cell lumens was investigated. The synthesis of ethylene maleic anhydride copolymer con­ taining pentachlorophenol (penta) and 8-hydroxy quino­ line (8HQ) in N, N dimethyl formamide is described. It was demonstrat...

Composite materials can be defined as a combination of two or more materials that results in better properties than those of the individual components used alone. These materials have high strength and stiffness combined with low density compared to the conventional metals. Polymers are structurally more complex than metals. Polymer – matrix composites are viscoelastic materials and their mecha...

Two significant advances are reported for solvent-based self-healing of epoxy materials. First, an autonomic system yielding complete recovery of fracture toughness after crack propagation was achieved by embeddingmicrocapsules containing amixture of epoxy monomer and solvent into an epoxy matrix. Healing with epoxy-solvent microcapsules is superior to capsules that contain solvent alone, and m...

A novel potentiometric solid-state reference electrode containing single-walled carbon nanotubes as the transducer layer between a polyacrylate membrane and the conductor is reported here. Single-walled carbon nanotubes act as an efficient transducer of the constant potentiometric signal originating from the reference membrane containing the Ag/AgCl/Cl(-) ions system, and they are needed to obt...

The stereoselectivity of reaction of methyl acrylate, methyl methacrylate and methyl transcrotonate with cyclopentadiene was studied with ab initio RHF/6-31G* and B3LYP/6-31G* levels of theory. The stereoselectivities predicted for methyl acrylate and methyl methacrylate with cyclopentadiene in the gas phase were found to be in good agreement with experimental results. The preference of endo se...

Until now, acrylates have been the monomers of choice for use for step and flash imprint lithography ~SFIL! etch barrier formulations, in part because of the commercial availability of silicon-containing acrylates ~necessary for etch resistance!, together with their low viscosities and capability for rapid photopolymerization. However, despite many desirable properties, the polymerization of ac...

The generated resist based defects on the template in addition to the presence of particles and contaminants is critical for ultraviolet curing of nanoimprint lithographic fabrication. This procedure is proven to be suitable for advanced resist material design under the process conditions. Nanoimprint resist material containing an ultraviolet reactive fluorine surfactant was developed to modify...

This paper presents the synthesis and thermal and mechanical properties of epoxy-titania composites. First, submicron titania particles are prepared via surfactant-free sol-gel method using TiCl₄ as precursor. These particles are subsequently used as inorganic fillers (or reinforcement) for thermally cured epoxy polymers. Epoxy-titania composites are prepared via mechanical mixing of titania pa...