We explore how a few-layer graphene can undergo phase transformation into thin diamond film under reduced or no pressure, if the process is facilitated by hydrogenation of the surfaces. Such a "chemically induced phase transition" is inherently nanoscale phenomenon, when the surface conditions directly affect thermodynamics, and the transition pressure depends greatly on film thickness. For the...

A substrate-free, large-scale, free-standing and two-side oriented single crystal rutile TiO(2) nanorod array film with a thickness of over ten micrometers, self-assembled via a facile hydrothermal reaction of titanium powder in a mixture solution of H(2)O(2) and HCl, exhibits high activity for the photocatalytic degradation of methyl orange.

We study the driven flow of an unentangled glassy polymer film with a free upper surface and supported below by a substrate using nonequilibrium molecular dynamics simulations based on a bead-spring model. Above the glass transition temperature T(g), simple Poiseuille laminar flow is observed with the film mobility defined as the flow current density per unit pressure gradient scaling as h(3) w...

The adsorbed film of 1-decyl-3-methylimidazolium bromide (DeMIMB) at the air/water interface was investigated employing the surface tension measurement and the x-ray absorption fine structure method under the total reflection condition (TRXAFS). From the surface tension measurement, the surface excess concentrations of ions were determined. From the XAFS measurement, two solvation states of bro...

The conductance of thin films with diffusive surface scattering was solved semiclassically by Fuchs and Sondheimer. However, when the intrinsic electron mean free path is very large or infinite their conductance diverges. In this Letter a simple diffraction picture is presented. It yields a conductance which corresponds to a limiting mean free path of a(2)/lambda(F), where a is the film thickness.

By combining supercritical drying technique with AAO template-assisted electrodeposition, noncollapsed, vertically aligned, and free-standing nanowire arrays on a conductive Au film have been fabricated. We also demonstrate that these free-standing nanowire arrays can be feasibly used for fabricating nanowire-based electrically driven devices.

The photocatalytic activity of an amorphous titanium oxide (a-TiOx) film was modified using a two-step deposition. The fluorinated base layer with a nano-textured surface prepared by a selective fluorination etching process acted as growth seeds in the subsequent a-TiOx deposition. A nanorod-like microstructure was achievable from the resulting a-TiOx film due to the self-assembled deposition. ...

Lamellar bodies, an intracellular source of lung alveolar surfactant, were isolated from rat lung homogenates and studied in the Langmuir-Adams surface balance. By layering intact lamellar bodies on the surface of a more dense sucrose subphase, we studied the factors affecting film formation from surface tension-vs-time data and determined surface tension-surface area isotherms by compression a...

We consider a simple model for a superlattice composed of a thin magnetic film placed between two bulk superconductors. The magnetic film is modelled by a planar but otherwise arbitrary distribution of magnetic dipoles and the superconductors are treated in the London approximation. Due to the linearity of the problem, we are able to compute the magnetic energy of the film in the presence of th...

Fourth order thin film equations can have late stage dynamics that are analogous to the classical Cahn–Hilliard equation. We undertake a systematic asymptotic analysis of a class of equations that describe partial wetting with a stable precursor film introduced by intermolecular interactions. The limit of small precursor film thickness is considered, leading to explicit expressions for the late...