The remarkably distinct reactivity of hydridozinc heterobimetallic cubanes [(HZnOtBu)4-n(thf LiOtBu)n] 1a-1d towards CO2 is reported--the hydride transfer from Zn-H to CO2 is drastically accelerated in the presence of Li ions in 1b-1d which led to the respective metal formate hydrates; the systems are inspiring models for the selective conversion of water gas into formates on lithium-promoted Z...

Gas hydrates are a costly problem when they plug oil and gas pipelines. The best way to determine the HFT and pressure is to measure these conditions experimentally for every gas system. Since this is not practical in terms of time and money, correlations are the other alternative tools. There are a small number of correlations for specific gravity method to predict the hydrate formation. As th...

Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO(2)) and/or production of methane (CH(4)) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH(4) and CO(2) hydrate (CH(4)-CO(2) mixed hydrates), as well as thermoph...

Raman spectroscopic measurements of simple hydrogen and tetrahydrofuran+hydrogen sII clathrate hydrates have been performed. Both the roton and vibron bands illuminate interesting quantum dynamics of enclathrated H(2) molecules. The complex vibron region of the Raman spectrum has been interpreted by observing the change in population of these bands with temperature, measuring the absolute H(2) ...

Prospective industrial applications of clathrate hydrates as materials for gas separation require further knowledge of cavity distortion, cavity selectivity, and defects induction by guest-host interactions. The results presented in this contribution show that under certain temperature conditions the guest combination of CH3F and a large polar molecule induces defects on the clathrate hydrate f...

The formation of gas hydrates is a major issue during the operation oil and pipelines, because cause plugging, thereby disrupting normal flows. A solution to inject hydrate inhibitors such as ionic liquids. Contrary classical inhibitors, liquids act both thermodynamic anti-agglomerates. Imidazolium-based have been found efficient for inhibition CO2 CH4 hydrates. For hydrates, N-ethyl-N-methylmo...