The catalytic combustion of H2/CO/O2/N2 mixtures over PdO was investigated at pressures 3 to 10 bar, H2:CO volumetric ratios 1:5 3:1, and global equivalence φ = 0.13 0.23. catalyst surface temperatures were controlled 540–690 K, a range especially important for hybrid hetero-/homogeneous approaches with large gas turbines idle or part-load operation microreactors recuperative small-scale turbin...

titania nanotubes (tnt) prepared by anodization of ti foils were used for water splitting in a standalone cell. the concentration polarization between the anode side (1m naoh) and cathode side (0.5 m h2so4) ensured that the water splitting reaction could take place with no external bias and separate h2 and o2 evolution could be achieved. the destruction of tnt structures under 365 nm uv irradia...

The MoFe protein from Azotobacter vinelandii catalyzes the reduction of methylene blue and other oxidants by H2 under anaerobic conditions. H2 uptake followed manometrically or by 3H2 transfer from the gas to aqueous phase occurs concomitantly with methylene blue disappearance monitored optically or coulometrically. The stoichiometry was found to be 1:1 methylene blue/H2. MoFe protein oxidized ...

Several researchers have shown that Pt-Rh bimetallic catalysts can perform synergistically for the NO/H2, NO/CO, CO/O2, and NO/CO/HC reactions [1-5]. Lakis and coworkers clarified some of the mystery surrounding the synergistic performance of Pt-Rh catalysts for the NO + H2 reaction by using analytical electron microscopy (AEM) to show that the synergistic performance of a Pt(95%)Rh(5%)/γ-Al2O3...

We modelled the kinetics of H2 flux during gas uptake and elimination in conscious pigs exposed to hyperbaric H2. The model used a physiological description of gas flux fitted to the observed decompression sickness (DCS) incidence in two groups of pigs: untreated controls, and animals that had received intestinal injections of H2-metabolizing microbes that biochemically eliminated some of the H...

laminar counterflow diffusion flames provide useful information about basic properties of non-premixed combustion. a lot of studies have been performed on h2/o2 counterflow. most of previous studies include undiluted or diluted systems of hydrogen (with co2 or n2) against an air flow under a variety of conditions such as strain rates, inlet temperature and pressure. the main purpose of this res...

The influence of pO2 on the base oxide formed 304 L stainless steel has been investigated at 600 °C. alloy was exposed in 5%O2-95%N2 and 10%H2-20%H2O-Ar atmospheres initial stages oxidation were analysed by TEM EDX. In both environments, thin scale consists a Cr-rich overlaid FeCrMn oxide. However, subscale H2-H2O is richer Cr compared to case (∼90 cation% ∼70 respectively). findings are good a...

The effect of H2 on isomerization pathways and on the acid site density on WOx-ZrO2 catalysts was explored using kinetic measurements of acid-catalyzed o-xylene isomerization reactions. Initial o-xylene isomerization rates on WOx-ZrO2 at 523 K are proportional to the H2 concentration even though H atoms are not involved directly in reaction turnovers, as shown by the low deuterium content in th...

Utilizing cyanobacteria as a bioenergy resource is difficult due to the cost and energy consuming harvests of microalgal biomass. In this study, an auto-floating system was developed by increasing the photobiological H2 production in the heterocysts of filamentous cyanobacteria. An amount of 1.0 μM of diuron, which inhibited O2 production in cyanobacteria, resulted in a high rate of H2 producti...