the photocatalytic process using semiconductors with a nanostructure is one of the technologies usedfor the destructive oxidation of organic compounds such as surfactants. in this paper, thephotocatalytic degradation of cetyl pyridinium chloride (cpc), was investigated in aqueous phaseusing various semiconductors such as titanium dioxide (ti02), zinc oxide (zno), stannic oxide(sn02). the degrad...

The effect of addition of sodium anthranilate to 5 mM micellar solutions of gemini surfactant 1,4-bis(N-hexadecyl-N,N-dimethylammonium)butane dibromide is investigated by 1H NMR. The solubilization site of anthranilate anion near the micellar surface is inferred. In the micelles, the An- ions intercalate among the surfactant headgroups producing morphological changes.

Series of benzoolysis experiments with 1,2-dipalmitoyl glycerophosphocholine (GPC), 1-palmitoyl-2-lyso GPC, and 1-O-hexadecenyl-2-oleoyl GPC, as well as a few experiments with 1-oleoyl-2-acetyl GPC and 1-O-hexadecyl-2-acetyl GPC are reported. The results are used to present a consistent picture of the various dephosphorylation and benzoylation reactions occurring in molten benzoic anhydride.

In the title salt, C(16)H(21)N(2)O(+)·Cl(-), the amide group makes a dihedral angle of 24.98 (2)° with respect to the pyridinium ring. In the crystal, both the amide and pyridinium N atoms are involved in N-H⋯Cl hydrogen bonding. Weak inter-molecular C-H⋯Cl and C-H⋯O inter-actions also occur.

1-O-Hexadecyl-2-O-methyl-3-O-(2'-amino-2'-deoxy-β-D-glucopyranosyl)-sn-glycerol (1) was previously reported to show potent in vitro antitumor activity on a range of cancer cell lines derived from breast, pancreas and prostate cancer. This compound was not toxic to mice and was inactive against breast tumor xenografts in mice. This inactivity was attributed to hydrolysis of the glycosidic linkag...

The enzyme phosphofructokinase-1 (PFK-1) catalyzes the first committed step of glycolysis and is regulated by a complex array of allosteric effectors that integrate glycolytic flux with cellular bioenergetics. Here, we demonstrate the direct, potent, and reversible inhibition of purified rabbit muscle PFK-1 by low micromolar concentrations of long chain fatty acyl-CoAs (apparent Ki∼1 μM). In sh...