In this paper, a novel Ni2P/black phosphorus (Ni2P/BP) supported on two-dimensional ?-zirconium phosphate (?-ZrP) hybrid material was prepared, and its catalytic activity for hydrodesulfurization (HDS) investigated. Through the reaction of nickel salt with BP nanosheets obtained by freeze-assisted exfoliation method, Ni2P nanoparticles can be formed firmly anchored surface BP, effectively preve...