نتایج جستجو برای: intrinsic equilibrium constant
تعداد نتایج: 431390 فیلتر نتایج به سال:
Label-free methods for evaluating lectin-cell binding have been developed to determine the lectin-carbohydrate interactions in the context of cell-surface oligosaccharides. In the present study, mass loading and electrochemical transducer signals were compared to characterize the interaction between lectin and cellular membranes by measuring the equilibrium association constant, Ka , between Ar...
Semiconductor photocatalytic process has been studied extensively in recent years due to its intriguing advantages in environmental remediation. In this study, a two-phase swirl-flow monolithic-type reactor is used to study the kinetics of photocatalytic degradation of benzoic acid in immobilized systems. Transport contributions into the observed degradation rates were determined when catalyst ...
1. The binding of Ca2+ to plasma coagulation Factor XIII from man and from cow caused a small decrease in the intrinsic fluorescence of the protein with a dissociation constant of 0.1 mM. A similar decrease was observed with the thrombin-activated Factors (Factors XIIa). The decrease in protein fluorescence was also caused by both Ni2+ and Mn2+ but not by Mg2+. 2. 45Ca2+ binding was directly de...
Although a number of procedures to create synthetic polymer nanoparticles (NPs) with an intrinsic affinity to target biomacromolecules have been published, little has been reported on strategies to control the binding kinetics of target recognition. Here, we report an enzyme-mimic strategy to control binding/dissociation rate constants of NPs, which bind proteins through multipoint interactions...
industrial wastewater included the dyes one of the important sources of environmental pollution that founded in loom wastewater which are harmful for human health and environment. therefore, the purpose of this research was investigated removal of rb5 dye from aqueous solution by using of adsorption onto activated red mud as an cheap adsorbent. this research was experimental- laboratorial study...
Reagentless biosensors rely on the interaction of a binding partner and its target to generate a change in fluorescent signal using an environment-sensitive fluorophore or Förster resonance energy transfer. Binding affinity can exert a significant influence on both the equilibrium and the dynamic response characteristics of such a biosensor. We here develop a kinetic model for the dynamic perfo...
Le Chatelier's principle is used as a very simple way to predict the effect of a change in conditions on a chemical equilibrium. . However, several studies have reported the violation of this principle, still there is no reported simple mathematical equation to express the exact condition of violation in the gas phase reactions. In this article, we derived a simple equation for the violation of...
the equilibrium moisture content is an important parameter for several post-harvesting operations for pistachio nuts, such as drying processes and storage. in this re-search the adsorption and desorption equilibrium moisture content were determined for two major varieties of iranian pistachios at 11 to 85 percent relative humidities and a con-stant temperature of 50°c. a significant hysteresis ...
The soft excess seen in many AGN is most probably due to partially ionized material moving at relativistic speeds close to the black hole. There are currently two potential geometries for this material, one where it is out of the line of sight, seen via reflection, e.g. the accretion disc, the other where it is in the line of sight, seen in absorption e.g. a wind above the disc. Both models req...
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