The first results are reported with a magnetic suspension instrument for determination of the viscosity and density concurrently on small volumes (0.2 ml) of protein solution. Reasonable agreement was obtained with literature values for the intrinsic viscosities and specific volumes (partial or isopotential) of serum albumin and ribonuclease in native solvents, and in 6 M guanidinium chloride w...

A new complex, manganese(II) azide complex with N-methylimidazole, has been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray studies. Absorption spectroscopy, emission spectroscopy, viscosity measurements and CD spectroscopy have been used to investigate the binding of the complex with calf thymus DNA (CTDNA). The intrinsic binding constant K(b) of the co...

The primary electroviscous effect has been investigated in dilute suspensions of titanium oxide (anatase), the viscosities of which were measured by means of a capillary viscometer with automatic timing. The linear relation between viscosity and solids volume fraction was first determined at the isoelectric point of the particles when the particles are uncharged, and the electroviscous contribu...

A novel photocrosslinkable and melt processible terpolymer precursor for carbon fiber has been successfully synthesized and characterized. The terpolymer was synthesized by an efficient emulsion polymerization route and has a typical composition of acrylonitrile/methyl acrylate/acryloyl benzophenone in the mole ratio, 85/14/1. It has been characterized by FTIR, NMR, intrinsic viscosity and GPC ...

Recent studies of globular protein solutions have uniformly adopted a colloidal view of proteins as particles, a perspective that neglects the polymeric primary structure of these biological macromolecules, their intrinsic flexibility, and their ability to sample a large configurational space. While the colloidal perspective often serves as a useful idealization in many cases, the macromolecula...

This article reports the effects of gamma irradiation (dose ranges 0.1-10 kGy from 60Co source) on the characteristics of solid gelatin and the physico-mechanical, microstructural and bioactive properties of the scaffold prepared from irradiated gelatin solution. FTIR, intrinsic viscosity, bloom strength, thermal properties, SEM, tensile properties, water uptake ability and antimicrobial activi...

The objective of this study was to formulate hyaluronate (HA) combined with magnesium sulfate (MS) for intra-articular (IA) injection, to provide rapid and profound analgesia in the treatment of osteoarthritis (OA). The injectable HA/MS combination was optimized with respect to the kinds and amounts of buffering agent (10 mM histidine, pH 7.0) and stabilizer (10 mM sodium citrate), by evaluatin...

−− Pectins are polysaccharides that act as a cellular binder in the peel of many different fruits and vegetables. An important feature of pectins is the esterification of the galacturonic acid residues with methanol. The degree of methylation is defined as the number of moles of methanol per 100 moles of galacturonic acid. The objective of the present work was to study the acid demethylation of...

This paper shows that acidic conditions provide substantially higher % acetyl content, intrinsic viscosity and thermoplasticity even at low ratios of acetic anhydride and catalyst concentrations compared to using alkaline conditions for acetylation of oil-and-zein-free distillers dried grains with solubles (DDGS). Conventional methods of carbohydrate and protein acetylation are unsuitable for a...

Experimental observations of driven and intrinsic rotation in tokamak plasmas are reviewed. For momentum sources, there is direct drive from neutral beam injection, lower hybrid and ion cyclotron range of frequencies waves (including mode conversion flow drive), as well as indirect j B × forces from fast ion and electron orbit shifts, and toroidal magnetic field ripple loss. Counteracting rotat...