A comprehensive model has been developed for calculating the thermal conductivity of aqueous, nonaqueous, and mixed-solvent electrolyte systems ranging from dilute solutions to fused salts or pure solutes. The model consists of a correlation for calculating the thermal conductivity of solvent mixtures and a method for predicting the effect of electrolyte components. The thermal conductivity of ...

Previously observed non-Arrhenius behavior in fast ion conducting glasses [J. Kincs and S. W. Martin, Phys. Rev. Lett. 76, 70 (1996)] occurs at temperatures near the glass transition temperature, T(g), and is attributed to changes in the ion mobility due to ion trapping mechanisms that diminish the conductivity and result in a decreasing conductivity with increasing temperature. It is intuitive...

Electrochemical nature of metallurgical reaction arouses more and more attentions, and the most closely related is the electrical conductivity of molten slag. The electrical conductivity of molten slag is not only an important physical property that plays a prominent role in modeling and operating the electric smelting furnace and optimizing the metallurgical process, but also important for und...

We present the electrical characterization of a zeolitelike oxo-vanadium arsenate framework. The experimentally obtained electronic and ionic conductivities and their interactions are discussed. Further, we investigate the potential use of electrically conducting zeolitelike materials in electrical energy storage applications, in light of the material’s structural and electronic characteristics...

In the electrolyte application for dye sensitized solar cells, utilization of ionic liquids is getting highlights to replace volatile organic solvent thanks their low volatility, thermal and electrochemical stability. The iodide/triiodide redox preferred choice this application, hence numerous iodide-based have been explored reported. On contrary, transport properties triiodide based liquid oft...

Lipid peroxidation (LPO) of unsaturated fatty acids in bimolecular lipid membranes (BLM), induced by ultraviolet irradiation [l-3] or by chemical agents [4], brings about an increase in conductivity of these membranes. For BLM prepared from egg phosphatidylcholine/cholesterol mixture this effect is accounted for by the rise of proton permeability [3,5]; the maximal conductivity enhancement bein...

We report on the efficiency of electrical power generation in individual rectangular nanochannels by means of streaming currents, the pressure-driven transport of counterions in the electrical double layer. Our experimental study as a function of channel height and salt concentration reveals that the highest efficiency occurs when double layers overlap, which corresponds to nanoscale fluidic ch...

In this paper, aggregation behaviors of aqueous solutions of short chain hydrophilic Ionic Liquids (ILs), 1 – allyl - 3 - methylimidazolium chloride ([Amim]Cl), 1 - ethyl - 3 - methylimidazolium chloride ([Emim]Cl), 1 - butyl - 3 - methylimidazolium chloride ([Bmim]Cl), 1 - butyl - 3 - methylimidazolium tetrafluoroborate ([Bmim]BF4) were investigated using conductivity and laser ...

Proton exchange membranes (PEMs) are a key component of a proton exchange membrane fuel cell. Sulfonated polyimides (SPIs) were doped by protic ionic liquid (PIL) to prepare composite PEMs with substantially improved conductivity. SPIs were synthesized from diamine, 2,2-bis[4-(4-amino-phenoxy)phenyl]propane (BAPP), sulfonated diamine, 4,4'-diamino diphenyl ether-2,2'-disulfonic acid (ODADS) and...

In this paper, the role of finite Electric Double Layer (EDL) conductivity on the Streaming Potential and the resulting Electroviscous effect in pressure-driven nanofluidic ionic transport is investigated. Important dimensionless parameters like the Dukhin number (based on the EDL surface electrical conductivity, the bulk electrical conductivity and the EDL thickness), ratio of the Stern Layer ...