Here we demonstrate that by regulating the mobility of classic -EO- based backbones, an innovative polymer electrolyte system can be architectured. This polymer electrolyte allows the construction of all solid lithium-based polymer cells having outstanding cycling behaviour in terms of rate capability and stability over a wide range of operating temperatures. Polymer electrolytes are obtained b...

Ionic liquid [Bmim][BF 4 ] and metal organic framework ZIF-8 ZIF-94 nanoparticles were incorporated into polymer Pebax® Renew® 30R51 to obtain highly efficient thin-film nanocomposite membranes, ca. 300 nm thick.

We use a phase-changing metal alloy to reversibly tune the elastic rigidity of an elastomer composite. The elastomer is embedded with a sheet of low-melting-point Field’s metal and an electric Joule heater composed of a serpentine channel of liquid-phase gallium–indium–tin (Galinstan R ) alloy. At room temperature, the embedded Field’s metal is solid and the composite remains elastically rigid....

Simple and highly efficient microvalve systems based on an ionic polymer-metal composite (IPMC) diaphragm actuator have been developed. The microvalve system that was fabricated in this work operates when open and close voltage is applied, due to the phenomena of lithium ion flux and the subsequent electro-osmotic drag of water to the cathode. IPMC was prepared by compositing with platinum nano...

This work reports on the healing of early stage fatigue damage in ionomer/nano-particulate composites. A series of poly(ethylene-co-methacrylic acid) zinc ionomer/Fe3O4 nanoparticle composites with varying amounts of ionic clusters were developed and subjected to different levels of fatigue loading. The initiated damage was healed upon localized inductive heating of the embedded nanoparticles b...

Low-cost and flexible solid polymer electrolytes are promising in all-solid-state Li-metal batteries with high energy density safety. However, both the low room-temperature ionic conductivities small Li+ transference number of these significantly increase internal resistance overpotential battery. Here, we introduce Gd-doped CeO2 nanowires large surface area rich oxygen vacancies to electrolyte...