The objective of this work was to obtain degradation kinetic models riboflavin and ascorbic acid, evaluate the potential front-face fluorescence (FFF) spectroscopy predict their concentration in milk after thermal processing. A factorial design with three temperatures (70, 80 90 °C) nine times (from 0 60 min) heat treatment used. Degradation kinetics both vitamins were first order. Predictive u...

Titanium dioxide nanoparticles surface-modified by 5-sulfosalicylic acid 5-SA-TiO2 were prepared in ethanol by the chemisorption process. The effects of surface improvement on the photocatalytic degradation and adsorption of methyl orange MO were studied in a batch system by considering the various parameters, such as contact time, adsorbent dosage, pH, initial dye concentration and temperature...

Light and temperature have considerable effect on the degradation of piroxicam in aqueous solutions. The pH and acetate buffer ions also affect the degradation process. The apparent first-order rate constants for the photochemical and thermal degradation of piroxicam have been determined as 2.04-10.01 and 0.86-3.06×10(-3) min(-1), respectively. The first-order plots for the degradation of pirox...

Ionomers are generally described by copolymers having either acrylic or methacylic acid as one component and the other component is mostly either ethylene or styrene. The objective of this research was to study the thermal behaviour and stability of ionomers of styrene with some alkali metal acrylates. These materials have been synthesized by neutralization of the respective copoly...

The conventional Navier-Stokes-Fourier equations with no-slip boundary conditions are unable to capture the phenomenon of gas thermal transpiration. While kinetic approaches such as the direct simulation Monte Carlo method and direct solution of the Boltzmann equation can predict thermal transpiration, these methods are often beyond the reach of current computer technology, especially for compl...

Laminate composites which are widely used in the aeronautical industry, are usually subjected to frequency variation of environmental temperature and excessive humidity in the in-service environment. The thermal fatigue and moisture absorption in composites may induce material degradation. There is a demand to investigate the coupling damages mechanism and characterize the degradation evolution...

In the present studies, silicon based low-density ablative material has been studied for its performance to protect flight hardware from temperature raises due aerodynamic forces a longer duration. The oxyacetylene flame test estimates properties at 100–120 W/m2 heat flux. time duration is taken 200 s. shows low mass and linear ablation rate with high effectiveness. degradation kinetics of abla...

Molecular simulation is becoming an important tool for both understanding polymeric structures and predicting their physical and mechanical properties. In this study, temperature ramped molecular dynamics simulations are used to predict two physical properties (i.e., glass transition temperature and thermal degradation temperature) of a previously synthesised and published telechelic benzoxazin...

Thermal degradation of as electrospun chitosan membranes and samples subsequently treated with ethanol and cross-linked with glutaraldehyde (GA) have been studied by thermogravimetry (TG) coupled with an infrared spectrometer (FTIR). The influence of the electrospinning process and cross-linking in the electrospun chitosan thermal stability was evaluated. Up to three degradation steps were obse...