نتایج جستجو برای: lewis acid
تعداد نتایج: 761908 فیلتر نتایج به سال:
The activation of π-bonds in diynyl esters has been investigated by using soft and hard Lewis acids. In the case of the soft selenium Lewis acid PhSeCl, sequential activation of the alkyne bonds leads initially to an isocoumarin (1 equiv PhSeCl) and then to a tetracyclic conjugated structure with the isocoumarin subunit fused to a benzoselenopyran (3 equiv PhSeCl). Conversely, the reaction with...
In the field of polyfunctional Lewis acids [1] the preorganisation of the Lewis acidic sites can be achieved employing rigid backbones. Ortho-substituted benzenes [2], peri-substituted naphthalene [3 – 6] and 1,8substituted anthracene [7, 8] offer promising applications as such backbones in the field of host-guest chemistry [9]. Furthermore, these frameworks can induce unusual interactions betw...
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