نتایج جستجو برای: mcm 41 supported catalyst
تعداد نتایج: 324330 فیلتر نتایج به سال:
Grafting of Co(NCCH3)2Cl2 onto mesoporous Ti-MCM-41 silica in acetonitrile solution affords binuclear Ti-O-Co sites on the pore surface under complete replacement of the precursor ligands by interactions with anchored Ti centers and the silica surface. The Co ligand field spectrum signals that the Co centers are anchored on the pore surface in tetrahedral coordination. FT-infrared action spectr...
Manganese (?) complex with 2, 2? bipyridine, 1, 1? dioxide (bpdo) ligand was immobilized within nanoreactors of MCM-41. The immobilized complex was characterized by powder x-ray diffraction (XRD), nitrogen adsorption desorption, and FTIR. The pore volume, surface area and pore diameter of MCM-41 decreased after immobilization of Mn complex. Three bands observed at 1250, 1220 cm?1 and 757 cm?1 a...
MCM-41-supported nanoscale zero-valent iron (nZVI) was sytnhesized by impregnating the mesoporous silica martix with ferric chloride, followed by chemical reduction with NaHB4. The samples were studied with a combination of characterization techniques such as powder X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) and Mössbauer spectroscopy, N2 adsorption measurements, transmission e...
برخی از آلاینده های آب و پساب با استفاده از روش های معمول و سنتی تصفیه از بین نمی روند؛ لذا استفاده از روش های نوین با کارایی بالاتر و هم سویی بیشتر با محیط زیست، مورد توجه محققان قرار گرفته است. هدف اصلی این پژوهش، بررسی کارایی حذف فنل از آب با استفاده از مواد کریستالی موبیل mcm-41)) عامل دار ti-mcm-41، fe-mcm-41،mcm-sic3h6nh2 و mo-mcm-41 و ماده mcm-41 بدون عامل کلسینه شده و نشده بود. در این ...
Fe3+-immobilized mesoporous molecular sieves MCM-41 with particle size of ca. 600 nm and pore size of ca. 3 nm is synthesized and applied to selectively trap and separate phosphopeptides from tryptic digest of proteins. For the capture of phosphopeptides, typically 10 microL of tryptic digest solution was first diluted to 1 mL by solution of ACN/0.1% TFA (50:50, v/v) and incubated with 10 micro...
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