A novel soft-hard cooperative approach was developed to synthesize bioactive mesoporous composite by pre-wrapping Penicillin G amidase with poly(acrylaimde) nanogel skin and subsequently incorporating such Penicillin G amidase nanocapsules into hierarchically mesoporous silica. The as-received bioactive mesoporous composite exhibited comparable activity and extraordinarily high stability in com...

This paper reports on the catalytic reaction for the conversion of silicon tetrachloride (STC) to trichlorosilane (TCS) over pretreated ordered mesoporous carbon (OMC) catalysts by oxygen (denoted as OMC-O2) and hydrochloric acid (denoted as OMC-HCl) at 300 degrees C under N2 atmosphere. The OMC-O2 shows significantly improved the surface area (1341.2 m2/g) and pore volume (1.65 cm3/g), which r...

Mesoporous aluminophosphate thin films templated by nonionic copolymer surfactant (Pluronic-F108 and –F127) were prepared by the dip-coating method. Self-assembly of copolymer surfactants with different sizes and hydrophilic properties into cubic symmetry causes the formation of thin films with different pore dimensions. Symmetry of pore arrangement was determined by SAXS and TEM measurements. ...

TiO2/Al-MCM-41 composites with various titania content were prepared by loading titania into the mesopores of Al-MCM-41 mesoporous molecular sieve from coal-measure kaolin as silicon and aluminum source via general sol-gel method and incipient wetness impregnation method. TiO2/Al-MCM-41 composites were characterized by XRD, FT-IR and SEM, and the photocatalytic degradation of methyl orange solu...

We report the synthesis and characterization of a series of new mesoporous zeolite and zeotype materials made available by combining new and improved procedures for directly introducing carbon into reaction mixtures with the fluoride route for conventional zeolite synthesis. The mesoporous materials were all prepared by hydrothermal crystallization of gels adsorbed on carbon matrices which were...

A magnetic nanoparticle conjugated mesoporous nanocatalyst (Fe(3)O(4)@mesoporous SBA-15) with a high surface area has been synthesized by chemical conjugation of magnetite (Fe(3)O(4)) nanoparticles with functionalized mesoporous SBA-15. Functionalized mesoporous SBA-15 containing surface carboxyl and amino groups was synthesized via the thiol-ene click reaction of cysteine hydrochloride and vin...

   In this research, mesoporous silica was served as the host of molybdate (corrosion inhibitor). The loaded mesoporous silica was dispersed in a paint matrix. The composite was then coated on the carbon steel surface. Polarization and electrochemical impedance spectroscopy (EIS) tests showed that the corrosion resistance of the scratched paint containing molybdate loaded mesoporous silica ...

Recently mesoporous materials have drawn great attention in fuel cell related applications, such as preparation of polymer electrolyte membranes and catalysts, hydrogen storage and purification. In this mini-review, we focus on recent developments in mesoporous electrocatalysts for polymer electrolyte membrane fuel cells, including metallic and metal-free catalysts for use as either anode or ca...

Ordered mesoporous carbon/iron oxide composites were prepared by cooperative self-assembly of poly(tbutyl acrylate)-block-polyacrylonitrile (PtBA-b-PAN), which contains both a carbon precursor block and a porogen block, and phenol-functionalized iron oxide nanoparticles (NPs). Because of the selective hydrogen bonding between the phenol-functionalized iron oxide NPs and PAN, the NPs were prefer...