Vanadium oxide-molybdenum oxide (VO-MO) thin (21-475 nm) films were grown on quartz and silicon substrates by pulsed RF magnetron sputtering technique by altering the RF power from 100 to 600 W. Crystalline VO-MO thin films showed the mixed phases of vanadium oxides e.g., V2O5, V2O3 and VO2 along with MoO3. Reversible or smart transition was found to occur just above the room temperature i.e., ...

The assimilatory nitrate reductase from Chlorella contains flavin, heme, and molybdenum as prosthetic groups. The molybdenum in assimilatory nitrate reductase is associated with a pterin moiety (molybdopterin) as evidenced by the ability of the enzyme to donate active molybdenum cofactor to the Neurospora nitrate reductase mutant nit-1 and by the oxidative conversion of the pterin to two well c...

Molybdenum (Mo), a bcc metal with a melting point of 2,610°C and a density of 10.22 g/cm, is an important refractory metal. The refractory properties of molybdenum reflect the high strength of interatomic bonding resulting from the overlap of the 4d-orbitals and the number of bonding electrons available (1). The melting point of molybdenum is exceeded only by those of tungsten and tantalum, amo...

Inspired by the ternary structure of natural nacre, robust ternary artificial nacre is constructed through synergistic toughening of graphene oxide (GO) and molybdenum disulfide (MoS2) nanosheets via a vacuum-assisted filtration self-assembly process. The synergistic toughening effect from high mechanical properties of GO and lubrication of MoS2 nanosheets is successfully demonstrated. Meanwhil...

One-step electrodeposition of crystalline zinc oxide thin films on Molybdenum/glass substrates in a low-cost ionic liquid, Reline composed of urea and choline chloride, is presented. X-ray diffraction spectroscopy shows the thin films have wurtzite structure. Raman microspectroscopy indicates a slight oxygen deficit in the film. Both X-ray energy dispersion and X-ray photonelectron spectroscopy...

A new potassium molybdenum oxide, K6Mo10O33, was synthesized by solid state reaction from the appropriate quantities of pre-dried MoO3 and K2MoO4, fired at around 650 ◦C for 2 d. The structure has been solved by using single crystal X-ray diffraction. The compound adopts the space group P1, with the lattice constants a = 7.7100(5), b = 11.9659(8), c = 17.1321(12) Å, α = 86.42 (10), β = 77.18(10...

Amorphous molybdenum sulfide (MoSx) is covalently anchored to reduced graphene oxide (r-GO) via a simple one-pot reaction, thereby inducing the reduction of GO and simultaneous doping of heteroatoms on the GO. The oxygen atoms form a bridged between MoSx and GO and play a crucial role in the fine dispersion of the MoSx particles, control of planar MoSx growth, and increase of exposed active sul...

The molybdenum nitrogenase, present in a diverse group of bacteria and archea, is the major contributor to biological nitrogen fixation. The nitrogenase active site contains an iron-molybdenum cofactor (FeMo-co) composed of 7Fe, 9S, 1Mo, one unidentified light atom, and homocitrate. The nifQ gene was known to be involved in the incorporation of molybdenum into nitrogenase. Here we show direct b...

The method for determining the mechanical and adhesion characteristics of particle-surface system based on a comparison results particle size measurements by two independent methods – electric mobility particles diffusion - was proposed experimentally tested. In first case, established an Electrostatic classifier (model TSI EC 3071A), in second it measured screen type battery (DB) 3041). Iodobe...