Human blood mononuclear cells, like monocytes, migrate into connective tissues during early steps of inflammation and locally interact with extracellular matrix macromolecules or their fragments (matrikines). These interactions, lead to differentiation of the monocytes either to macrophages (MF) or to dendritic cells (DC). Extracellular matrix compounds are able to modulate the mononuclear cell...

The synthesis, structure, and luminescent propertiesof a samarium(III) complex (A2) containing benzoyltrifluoroacetone (HTFPB) 1,2-bis[(anthracen-9-ylmethyl)amino]ethane (BAAE2) ligands are herein reported. structure of A2 has been elucidated by infrared spectroscopy single crystal X-ray diffraction. crystallographic analysis demonstrated that mononuclear with formula Sm(TFPB)3(BAAE2) in which ...

Abstract In continuation of the study focused on synthesis and structure mimics active site [FeFe] hydrogenase enzyme, reaction Fe 3 (CO) 12 with cyclopropyl ferrocenyl thioketone 1 was carried out. Two different complexes ring‐opened fragments were isolated identified as η 4 ‐1‐thia‐1,3‐diene‐type mononuclear tricarbonyl iron complex 2 ‐acyl‐type hexacarbonyl diiron , respectively. Structures ...

The mononuclear cobalt(III) complex derived from 1,10-phenanthroline and maltose ([Co(phen)2maltose]Cl2∙3H2O) (1) has been synthesized and characterized in aqueous solution. Its characterization was based on its optical and spectroscopic properties. The antimicrobial activity of this complex was screened in vitro against the microorganisms Escherichia coli DH5a, Salmonella enterica sv Enteritid...

The identity of human bone marrow (BM)-derived T cell precursors with colony forming capacity has led to controversy because of contamination with mature clonogenic T cells. We achieved 2 Log elimination of mature T cells from BM using a cocktail of monoclonal antibodies: CD2, CD3, CD4, CD6, and CD8 followed by two successive baby rabbit C' treatment. T cell depleted BM can generate colonies of...

Mononuclear lanthanide (Ln) complexes can be high-performing single-molecule magnets (SMMs). Recently, there has been an influx of mononuclear Ln alkoxide and aryloxide SMMs. Here, DyIII SMMs with coordination numbers up to eight are covered in detail, additional brief overviews TbIII, HoIII, ErIII YbIII For more information, see the review by V. S. Parmar, D. P. Mills R. E. Winpenny on page 76...