This paper presents new findings on ultrasonic spray pyrolysis of zirconium hydroxyl acetate precursor drops whose sizes were precisely measured using laser light diffraction technique. Precursor concentration plays a predominant role in determination of product particle size. At 0.01 wt% precursor concentration, conventional spray pyrolysis at 750°C using precursor drops 5–8 !m in diameter, ge...

A novel fabrication method using electroless and electrodeposited Ni/Ag/GDC for SOFC anodes is presented. First a porous Ce0.9Gd0.1O2 x (GDC) scaffold was deposited on a YSZ electrolyte by screen printing and sintering. The scaffold was then metallized with silver using Tollens' reaction, followed by electrodeposition of nickel from a Watt's bath. The electrodes (Ni/Ag/GDC) were tested in both ...

A strong correlation exists between the performance of Solid Oxide Cells (SOCs), working either in fuel cell or electrolysis mode, and their electrodes microstructure. However, the basic relationships between the three-dimensional characteristics of the microstructure and the electrode properties are not still precisely understood. Thus, several studies have been recently proposed in an attempt...

This study investigated the feasibility of depositing graphene nanoplatelet (GNP)-reinforced yttria-stabilized zirconia (YSZ) composite coatings. The coatings were deposited from an ethanol-based mixed YSZ and GNP suspension using plasma spraying (SPS). Raman spectroscopy confirmed presence GNPs in matrix, scanning electron microscopy (SEM) analysis revealed a desired columnar microstructure wi...

Y2O3-stabilized ZrO2 (YSZ) ceramics have been used for various engineering applications or as a solid electrolyte in oxygen sensors and fuel cells. The performance YSZ strongly depends on the microstructure which is directly determined by characteristic of raw powder. In this paper, synthetic methods powder its starting material are first overviewed, then formation mechanism explained, focusing...

The present in situ study of electrochemically induced processes occurring in Cr/Ni bilayers in contact with a YSZ electrolyte aims at a molecular-level understanding of the fundamental aspects related to the durability of metallic interconnects in solid oxide fuel cells (SOFCs). The results demonstrate the potential of scanning photoelectron microspectroscopy and imaging to follow in situ the ...

Yttria-stabilized zirconia (YSZ) has been used as a thermal/environmental barrier coating for gas turbine engine blades. Current methods of fabrication include air plasma spraying (APS) and electron-beam physical vapor deposition (EB-PVD). The APS technique results in a coating that loses effectiveness with thermal cycling. The EB-PVD technique deposits a columnar microstructure which accommoda...