Raman gain for all-optical amplification depends significantly on the cross section for spontaneous Raman scattering. We present measurements of the Raman spectrum of binary niobium-phosphate glasses in the frequency range from 5 – 1300 cm. The spectra of these glasses show a low-frequency enhancement of the vibrational density of states (‘Boson peak’) suggesting a significant gain profile for ...

Dielectric multilayer coatings exhibiting steep reflectance in an extremely narrow transition zone, highly sensitive to any variations of layer refractive indices and therefore suitable for studying the nonlinear properties are produced and characterized. Increase of reflectance at growing intensity reveals the presence of the optical Kerr effect. A new method calculating intensity dependent sp...

A second addition of lmol% of CoO to a pre calcined SnO2-based ceramic doped with 1.0mol% of CoO, 0.05mol% of Nb2O5 and 0.05mol% of Cr2O3 promotes the appearance of a secondary phase, Co2SnO4, besides the SnO2 cassiterite phase, when the ceramic was sintered at 1350°C/2h. This was observed using X-ray powder diffraction, scanning electron microscopy and energy dispersive X-ray techniques. Rietv...

Tellurite TeO2–TiO2–Nb2O5 thin film glasses have been produced by pulsed laser deposition. The dispersion of the real and imaginary parts of the linear refractive index has been measured in the range from 300 to 1700 nm. Films present high refractive index n=2.01 and reduced absorption k 10−4 at =1500 nm. The nonlinear third order optical susceptibility 3 has been determined at four different w...

The binary tantalum–oxygen system is assessed using the CALculation of PHase Diagrams (CALPHAD) method with experimental data from literature. oxygen solubility in Ta solid-solution phase discussed and modeled. low- high-temperature modifications Ta2O5 are described as stoichiometric compounds. This dataset extended into ternary Al–Ta–O by complementing it datasets for Al–O Al–Ta literature add...

A multichannel mixed-conducting hollow fiber (MMCHF) membrane, 0.5 wt % Nb2O5-doped SrCo0.8 Fe0.2O3-d (SCFNb), has been successfully prepared by phase inversion and sintering technique. The crystalline structure, morphology, sintering behavior, breaking load, and oxygen permeability of the MMCHF membrane were studied systematically. The MMCHF membrane with porous-dense asymmetrical microstructu...

A triple-layer composite membrane with porous-dense-porous structure was proposed to develop a high performance membrane reactor. The triple-layer composite membrane consists of a porous Sr0.7Ba0.3Fe0.9Mo0.1O3 δ (SBFM) layer, a dense 0.5 wt% Nb2O5-doped SrCo0.8Fe0.2O3 δ (SCFNb) layer and a porous La0.8Sr0.2MnO3 δ–yttria stabilized zirconia (LSM/YSZ) layer. The porous layers can effectively redu...