Research on interstellar ND3 is reviewed and updated from the discovery papers. Results from observations of a dozen sources at centimeter and submillimeter wavelengths are presented. The two data sets are consistent, but do not constrain the excitation conditions in the ND3emitting gas. The column density ratios of NH3/NH2D, NH2D/ND2H and ND3/ND2H, observed in similar sized beams, are ≈10, and...

Most work on high-mass star formation has focused on observations of young massive stars in protoclusters. Very little is known about the preceding stage. Here, we present a new high-resolution study of pre-protocluster regions in tracers exclusively probing the coldest and dense gas (NH2D). The two target regions G29.96−0.02 and G35.20−1.74 (W48) are drawn from the SCAMPS project, which search...

A resistive sensor based on films of carbon gel-TiO2 nanocomposites prepared with different percentages TiO2 by a sol-gel process, was developed to determine ammonia gas. thin film dispersed in poly(vinylidenfluoride) and deposited glass slides containing silver electrodes are used as NH3 sensor. The resistance the at potential difference 1.0 V determined presence NH3, CO2, C2H5OH, CH3OH, C4H10...

the chemical composition, in situ  rumen degradability coefficients of dry matter (dm) and crude protein (cp), in vitro gas production and in vivo  digestibility were evaluated for olive cake (oc) silage treated (dm basis) with different additives as follows: (1) untreated oc; (2) oc, 8% molasses and 0.4% formic acid and (3) oc, 8% molasses, 0.4% formic acid and 0.5% urea. after addition of the...

A USDA Natural Resources Conservation Service, Conservation Innovation Grant project coordinated by the United Egg Producers (UEP) conducted concurrent demonstrations in Iowa and Pennsylvania (PA) at commercial laying hen facilities. The goal was to document manure nutrient and gas emission improvements through the use of dried distiller’s grain with solubles (DDGS) diets and/or other dietary m...

Ammonia was used for the major absorbent while sodium hydroxide was used as a reference in either a bubble column (semi-batch reaction) or a packed tower (continuous reaction) to absorb CO2 in this study. In the bubble column, bubbling time as a function of temperature, pH, and dissolved inorganic carbon concentration in the solution was measured to see the characteristics of the reaction and t...

A mixture of acetylene, hydrogen and ammonia C2H2/H2/NH3 is used to produce carbon nanotubes (CNTs) by a plasma-enhanced catalytic chemical vapor deposition process with hot-filaments assistance (PE HF CCVD). The investigation of gas phase and surface chemistry is performed by CHEMKINTM software. The concentration of gas phase species on the substrate is presented. Based on this study the role ...

This paper is aimed at selectivity investigation of gas sensors, based on chemically modified nanocrystalline tin dioxide in the detection of CO and ammonia mixtures in air. Sol-gel prepared tin dioxide was modified by palladium and ruthenium oxides clusters via an impregnation technique. Sensing behavior to CO, NH3 and their mixtures in air was studied by in situ resistance measurements. Using...

UNLABELLED Nitrosomonas europaea is a chemolithoautotrophic bacterium that oxidizes ammonia (NH3) to obtain energy for growth on carbon dioxide (CO2) and can also produce nitrous oxide (N2O), a greenhouse gas. We interrogated the growth, physiological, and transcriptome responses of N. europaea to conditions of replete (>5.2 mM) and limited inorganic carbon (IC) provided by either 1.0 mM or 0.2...

The energetics of the Menshutkin-like reaction between four mesylate derivatives and ammonia have been computed using B3LYP functional with the 6-31+G** basis set. Additionally, MPW1K/6-31+G** level calculations were carried out to estimate activation barrier heights in the gas phase. Solvent effect corrections were computed using PCM/B3LYP/6-31+G** level. The conversion of the reactant complex...