To perform a quantitative simulation using the Phase Field Method (PFM) in a real alloy system, a new strategy of modeling the microstructure evolution of Ni-base superalloy is proposed in the present paper. In this strategy, the Calculation Phase Diagram (CALPHAD) method and Cluster Variation Method (CVM) are combined with the PFM, in which the four sub-lattice model is used to evaluate the fr...

The effects of a 2.0 at.% addition of Ta to a model Ni–10.0Al–8.5Cr (at.%) superalloy aged at 1073 K are assessed using scanning electron microscopy and atom-probe tomography. The c0(L12)-precipitate morphology that develops as a result of c-(fcc)matrix phase decomposition is found to evolve from a bimodal distribution of spheroidal precipitates, to {001}-faceted cuboids and parallelepipeds ali...

The effect of -Al2O3 particles on the electrochemical codeposition behaviour of Co–Ni alloys from sulfamate electrolyte was investigated by codeposition experiments, zeta potential and electrochemical methods. The results indicate that the presence of Al2O3 particles in Co–Ni sulfamate electrolytes contributes to the preferential codeposition of Co. Moreover, increasing Co2+ concentration also ...

The effect of pulse electrodeposition parameters on the composition and microstructure of Ni–Re alloys were studied on a rotating cylinder electrode. Ni–Re alloys were deposited from a citrate bath where the nickel-to-rhenium ratio was 45:1. The composition of the deposited alloy was monitored by energy dispersive spectroscopy (EDS) and compared to a single component transport-based model descr...

Steam reforming of light hydrocarbons provides a promising method for hydrogen production. Ni-based catalysts are so far the best and the most commonly used catalysts for steam reforming because of their acceptably high activity and significantly lower cost in comparison with alternative precious metal-based catalysts. However, nickel catalysts are susceptible to deactivation from the depositio...

Density functional theory is employed to study Pd and Pd/Ni alloy monatomic axial and circular chain-functionalized metallic single walled carbon nanotube SWNT(6,6) and semi-conducting SWNT(10,0), and their interactions with hydrogen molecules. The stable geometries and binding energies have been determined for both isolated chains and chains on SWNT surface. We found that both axial and radial...

Intermetallic compounds are increasingly being expected to be utilized in tribological environments, but to date their implementation is hindered by insufficient ductility at low and medium temperatures. This paper presents a novel multiphase intermetallic alloy with the chemical composition of Mo-40Ni-13Si (at %). Microstructure characterization reveals that a certain amount of ductile Mo phas...

Soft magnetic properties of Fe-Co-Ni-Al-Cr-Si thin films were studied. As-deposited Fe-Co-Ni-Al-Cr-Si nano-grained thin films showing no magnetic anisotropy were subjected to field-annealing at different temperatures to induce magnetic anisotropy. Optimized magnetic and electrical properties of Fe-Co-Ni-Al-Cr-Si films annealed at 200 ◦C are saturation magnetization 9.13 × 105 A/m, coercivity 79...

The amorphous ternary metallic alloy Zr60Al15Ni25 was oxidized in dry oxygen in the temperature range 310 ±C to 410 ±C. Rutherford backscattering (RBS) and cross-sectional transmission electron microscopy (TEM) studies suggest that during this treatment an amorphous layer of zirconium-aluminum-oxide is formed at the surface. Nickel was depleted in the oxide and enriched in the amorphous alloy n...

We have investigated the effect of pressure and thermal ageing on transformation behavior of Ni-%45.16Ti shape memory alloy. 70-320 MPa pressure was applied and annealed at 500 o C for 2 hour to see the effect of applied pressure on transformation temperature. It was observed that the starting and final temperature of austenit increased, the martensite start temperature almost remain constant a...