Thermodynamics is a core part of most science and engineering curricula. However, most texts that are currently available to students still treat thermodynamics very much as it was presented in the 19th century,...

2 Thermodynamics 4 2.1 The Foundations of Thermodynamics . . . . . . . . . . . . . . . 4 2.2 Thermodynamic Equilibrium . . . . . . . . . . . . . . . . . . . . 5 2.3 The Conditions for Equilibrium . . . . . . . . . . . . . . . . . . . 7 2.4 The Equations of State . . . . . . . . . . . . . . . . . . . . . . . . 13 2.5 Thermodynamic Processes . . . . . . . . . . . . . . . . . . . . . . 14 2.6 Ther...

Let h be a finite dimensional complex Hilbert space, b(h)+ be the set of all positive semi-definite operators on h and Phi is a (not necessarily linear) unital map of B(H) + preserving the Entropy-Gibbs transformation. Then there exists either a unitary or an anti-unitary operator U on H such that Phi(A) = UAU* for any B(H) +. Thermodynamics, a branch of physics that is concerned with the study...

Exergy analysis is based on combined first and second laws of thermodynamics and is a useful tool to analyze the energy systems in a better and more realistic way than an energy analysis, based on the first law of thermodynamics. Combination of exergy from thermodynamics with conventional concepts from engineering economy which is referred to as thermo-economy (exergo-economy) is a valuable too...

Exergy analysis is based on combined first and second laws of thermodynamics and is a useful tool to analyze the energy systems in a better and more realistic way than an energy analysis, based on the first law of thermodynamics. Combination of exergy from thermodynamics with conventional concepts from engineering economy which is referred to as thermo-economy (exergo-economy) is a valuable too...

In order to assess the disposal of spent nuclear fuel in a deep geological waste repository, interactions between U(VI) and corroded iron present canister material are importance. It is important correctly model fate oxidatively dissolved uranium estimate radium releases from long term. The release radionuclides into environment depends on dissolution UO2 matrix which dependent redox conditions...