We describe the synthesis of two cyclobutadiene(cyclopentadienyl)cobalt-containing poly(p-phenylene ethynylene)s (PPEs) and their use as precursors for stable ceramic surface coatings. Organometallic PPEs were shaped into hexagonally ordered assemblies by using the breath-figure method. Such breath figures can be washed away with an appropriate solvent. Upon pyrolysis at 500 degrees C under eit...

The implementation of the Montreal Protocol, the Clean Air Act, and the Pollution Prevention Act of 1990 has resulted in increased awareness of organic solvent use in chemical processing. The advances made in the search to find "green" replacements for traditional solvents are reviewed, with reference to solvent alternatives for cleaning, coatings, and chemical reaction and separation processes...

Buildings that simultaneously provide natural illumination and thermal comfort for all seasons have met with increasing demand as conventional resource limitations are realized. In this context, organic and metal-dielectric coatings are tested, and a simple, coated double-glazed window with solar blinds is conceived that includes passive infrared (IR) reflection, active illumination control, an...

A novel synthetic route to polymer-coated ferromagnetic colloids of metallic cobalt has been developed. Well-defined end-functional polystyrenes were synthesized using controlled radical polymerization and used as surfactants in the thermolysis of dicobaltoctacarbonyl to afford uniform ferromagnetic nanoparticles. The presence of the polymer shell enabled prolonged colloidal stability of disper...

ni-w coatings, compared to pure nanocrystalline ni, exhibit higher hardness and wear resistance. in some cases, these coatings are considered as environmental friendly alternatives for hard chromium coating. till now, most of ni-w coatings have been produced by direct current electrodeposition from alkaline baths. in this study square pulse current was used for deposition of ni-w precipitates f...