Multilayered Al/Cu/Fe thin films have been deposited by magnetron sputtering onto Si and Al2O3 substrates with a nominal global composition corresponding to the quasicrystalline phase, 5:2:1. Subsequent annealing was performed on samples up to 710 °C. It is found that when using Si as substrate a film-substrate reaction occurs already below 390 °C, where Si diffuses into the film. This changes ...

The chain polymer [{Cd(μ-X)2py2}∞] (X = Cl, Br; py = pyridine) undergoes a fully reversible phase transition between a monoclinic low-temperature and an orthorhombic high-temperature phase. The transformation can be directly monitored in single crystals and can be confirmed for the bulk by powder diffraction. The transition temperature can be adjusted by tuning the composition of the mixed-hali...

In high performance thin layer chromatography some form of optimization is necessary if complete separation of all components is required. The selection of mobile phase composition is one of the most important components of an optimization strategies. The aim of this paper is the separation of the N-alkyl phenothiazine sulfones by high performance thin layer chromatography using an optimum mobi...

We discuss techniques for managing and visualizing x-ray diffraction spectrum data for thin film composition spreads which map large fractions of ternary compositional phase diagrams. An in-house x-ray microdiffractometer is used to obtain spectra from over 500 different compositions on an individual spread. The MATLAB software is used to quickly organize the data and create various plots from ...

Paramagnetic resonance spectra of spin labels partitioned into spheroplast membranes of Bacillus stearothermophilus indicate lateral lipid phase separations. Cells adjust their lipid composition in response to temperature changes so that the same change of state in membrane phospholipids is achieved at the respective growth temperature. A temperature-sensitive mutant that fails to change its li...

An endothermic phase change in the presence of chemical heterogeneitles can act as an efficient filter, such that heavy material is sequestered below the phase change and light material is trapped above the phase change. Due to the fact that the endothermlc phase change damps thermal convection, it can act as a "trap door" for chemical heterogeneitles Ascending flows which are chemically dense ...

We propose a novel, to our knowledge, method for the determination of tie lines in a phase diagram of ternary lipid mixtures. The method was applied to a system consisting of dioleoylphosphatidylcholine (DOPC), egg sphingomyelin (eSM), and cholesterol (Chol). The approach is based on electrofusion of single- or two-component homogeneous giant vesicles in the fluid phase and analyses of the doma...

One of the most extensively studied silicate systems with complete miscibility in solid and liquid state – albite (Ab)-anorthite (An) system has been analyzed detail. It established that commonly accepted interpretation rules for these diagrams do not match their graphic representation. Calculations have proved colloidal “solid” phase on solidus. Actual data support (liquid) solidus below eutec...

since its advent in 1867,the arabic novel has been under the influence of two factors. one factor is longing for the past, the other one is infatuation with the west and submission to its hegemony. in early 20th century, some novels were written in response to public taste and arab culture. this novel is considered by critics of fiction to be a turning point in the path of arabic fiction. at th...

synthesis of bafe12o19 magnetic nano particles via precipitation in different ph conditions have been reported. the certain molar ratio of fe/ba = 12 selected and sodium hydroxide was used as a precipitant agent. x-ray diffraction (xrd), scanning electron microscopy (sem) and vibrating sample magnetometer (vsm) were used to consider the structural, morphological and magnetic properties of bariu...