نتایج جستجو برای: photochemical oxidation

تعداد نتایج: 126898  

2016
Bo Y. Chang Ignacio R. Sola Seokmin Shin Andre Bandrauk

A new perspective on how to manipulate molecules by means of very strong laser pulses is emerging with insights from the so-called light-induced potentials, which are the adiabatic potential energy surfaces of molecules severely distorted by the effect of the strong field. Different effects appear depending on how the laser frequency is tuned, to a certain electronic transition, creating light-...

Journal: :Chemistry 2013
Gábor London Kuang-Yen Chen Gregory T Carroll Ben L Feringa

We report the synthesis of altitudinal molecular motors that contain functional groups in their rotor part. In an approach to achieve dynamic control over the properties of solid surfaces, a hydrophobic perfluorobutyl chain and a relatively hydrophilic cyano group were introduced to the rotor part of the motors. Molecular motors were attached to quartz surfaces by using interfacial 1,3-dipolar ...

Journal: :Precambrian Research 2021

It is widely accepted that atmospheric pO2 < 1 ppm before the Great Oxidation Event. Yet a recent study found fossil micrometeorites (MMs) containing oxidized iron species wüstite (FeO) and magnetite (Fe3O4) formed 2.7 billion years ago (Ga). How these MMs became uncertain. Abundant O2 in upper atmosphere oxidation by CO2 have been suggested. However, photochemical reactions cannot produce suff...

2010
Julien Roeser Rainer Bischoff Andries P. Bruins Hjalmar P. Permentier

Oxidation of proteins and peptides is a common phenomenon, and can be employed as a labeling technique for mass-spectrometry-based proteomics. Nonspecific oxidative labeling methods can modify almost any amino acid residue in a protein or only surface-exposed regions. Specific agents may label reactive functional groups in amino acids, primarily cysteine, methionine, tyrosine, and tryptophan. N...

2015
Marta Gmurek Magdalena Olak-Kucharczyk Stanisław Ledakowicz

BACKGROUND In the last few decades the quality of natural water has often deteriorated as a variety of novel pollutants have contaminated rivers and lakes. Trace amounts of some man-made chemicals can be hazardous to plants, animals as well as human health as carcinogens, mutagens or endocrine disruptors. Light radiation may help in its decomposition, aided by naturally occurring colored organi...

Journal: :Icarus 1988
Y L Yung R R Friedl J P Pinto K D Bayes Wen J-S

It is argued that photochemical processes, driven by ultraviolet starlight, could lead to large deuterium fractionation for H2O and CH4 relative to H2 in the primitive solar nebula. Implications for deuterium enrichment observed in planetary atmospheres are briefly discussed.

Journal: :Proceedings of the National Academy of Sciences of the United States of America 2017
Yuemeng Ji Jun Zhao Hajime Terazono Kentaro Misawa Nicholas P Levitt Yixin Li Yun Lin Jianfei Peng Yuan Wang Lian Duan Bowen Pan Fang Zhang Xidan Feng Taicheng An Wilmarie Marrero-Ortiz Jeremiah Secrest Annie L Zhang Kazuhiko Shibuya Mario J Molina Renyi Zhang

Photochemical oxidation of aromatic hydrocarbons leads to tropospheric ozone and secondary organic aerosol (SOA) formation, with profound implications for air quality, human health, and climate. Toluene is the most abundant aromatic compound under urban environments, but its detailed chemical oxidation mechanism remains uncertain. From combined laboratory experiments and quantum chemical calcul...

In order to evaluate the effects of both cold and light stresses on chlorophyll fluorescence and feasibility of using chlorophyll florescence technique to evaluate effect of light intensity on cold tolerance in soybean, an experiment was done in a factorial arrangement based on a completely randomized design with three replicates. Two soybean cultivars consisted of 032 and BP grown under greenh...

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